Photophysical and Thermal Properties of Polyazomethines Containing Various Flexible Units

İsmet Kaya; Ali Avcı; Kevser Temizkan

Macromolecular Research, Vol.25, No.1, 45-53, January, 2017

DOI10.1007/s13233-017-5002-3 Export Citation

Photophysical and Thermal Properties of Polyazomethines Containing Various Flexible Units

İsmet Kaya^{1, †}, Ali Avcı^{1, 2}, and Kevser Temizkan¹

¹Polymer Synthesis and Analysis Laboratory, Department of Chemistry, Çanakkale Onsekiz, Mart University, 17020 Çanakkale, Turkey
²Department of Chemistry, Faculty of Sciences and Arts, Celal Bayar University, 45140, Manisa, Turkey

E-mail:

In this study, the poly(azomethine-ether-urethane), poly(azomethine-ester) and poly(azomethine-epoxyether) compounds were prepared to investigate effect of various flexible units on some physical properties like thermal stability and photophysical properties. Structural characterizations were made by FTIR, 1H NMR, 13C NMR, and UV-Vis analyses. The molecular weight distributions of polymers were performed by gel permeation chromatography (GPC) measurement. The chemical and physical properties of polymers were examined by thermogravimetry (TG), differential scanning calorimetry (DSC), photoluminescence (PL), dynamic mechanical analysis (DMA), scanning electron microscope (SEM) and atomic force microscopy (AFM) techniques. As a result, the outstanding properties related to the photoluminescence and thermal measurements of the polymers were obtained. Therefore, the presented photoluminescent polymers could be used in thermally stable photo-functional materials.

Keywords:polyazomethines;photophysical properties;thermally stable polymers;scanning electron microscope (SEM);photoluminescence

[References]

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Dogan F, Kaya I, Bilici A, Yıldırım M, J. Polym. Res., 22, 104 (2015)
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Cihaner A, Algi F, J. Electroanal. Chem., 614(1-2), 101 (2008)
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Rizzo A, Solin N, Lindgren LJ, Andersson MR, Inganas O, Nano Lett., 10, 2225 (2010)
Issam AM, Ismail J, J. Appl. Polym. Sci., 100(2), 1198 (2006)
Kobzar YL, Tkachenko IM, Bliznyuk VN, Shekera OV, Turiv TM, Soroka PV, Nazarenko VG, Shevchenko VV, Des. Monomers Polym., 19, 1 (2016)
Xiang T, Liu X, Yi P, Guo M, Chen Y, Wesdemiotis C, Xu J, Pang Y, Polym. Int., 62, 1517 (2013)
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[1] Jiang Y, Gao Y, Tian HK, Ding JQ, Yan DH, Geng YH, Wang FS, Macromolecules, 49(6), 2135 (2016)

[2] Culhaoglu S, Kaya I, Polym. Korea, 39(2), 225 (2015)

[3] Liang YY, Wu Y, Feng DQ, Tsai ST, Son HJ, Li G, Yu LP, J. Am. Chem. Soc., 131(1), 56 (2009)

[4] Hellstrom S, Lindgren LJ, Zhou Y, Zhang FL, Inganas O, Andersson MR, J. Polym. Sci. A: Polym. Chem., 1, 1272 (2010)

[5] Adhikari B, Majumdar S, Prog. Polym. Sci, 29, 699 (2004)

[6] Dogan F, Kaya I, Bilici A, Yıldırım M, J. Polym. Res., 22, 104 (2015)

[7] Ram MK, Sundaresan NS, Malhotra BD, J. Mater. Sci. Lett., 13(20), 1490 (1994)

[8] Cihaner A, Algi F, J. Electroanal. Chem., 614(1-2), 101 (2008)

[9] Wang Y, Jing X, Polym. Adv. Technol., 16, 344 (2005)

[10] Rizzo A, Solin N, Lindgren LJ, Andersson MR, Inganas O, Nano Lett., 10, 2225 (2010)

[11] Issam AM, Ismail J, J. Appl. Polym. Sci., 100(2), 1198 (2006)

[12] Kobzar YL, Tkachenko IM, Bliznyuk VN, Shekera OV, Turiv TM, Soroka PV, Nazarenko VG, Shevchenko VV, Des. Monomers Polym., 19, 1 (2016)

[13] Xiang T, Liu X, Yi P, Guo M, Chen Y, Wesdemiotis C, Xu J, Pang Y, Polym. Int., 62, 1517 (2013)

[14] Khuhawar MY, Mughal MA, Channar AH, Eur. Polym. J., 40, 805 (2004)

[15] Kaya I, Uysal S, J. Appl. Polym. Sci., 120(6), 3325 (2011)

[16] Tripathi SM, Tiwari D, Ray A, Indian J. Chem., 53, 1505 (2014)

[17] Kaya I, Yıldırım M, Aydm A, Org. Electron., 12, 210 (2011)

[18] Kaya I, Kamaci M, Arican F, J. Appl. Polym. Sci., 125(1), 608 (2012)

[19] Iqbal R, Khosa MK, Jamal MA, Ilyas S, Hussain MT, Hamid M, Polym. Adv. Technol., 27, 221 (2016)

[20] Farcas A, Resmerita AM, Aubert PH, Ghosh I, Cantin S, Nau WM, Macromol. Chem. Phys., 216, 662 (2015)

[21] Kaya I, Avci A, Kolcu F, Culhaoglu S, Des. Monomers Polym., 17, 481 (2014)

[22] Li CH, Chang TC, J. Polym. Sci. A: Polym. Chem., 29, 361 (1991)

[23] Suhas DP, Jeong HM, Aminabhavi TM, Raghu AV, Polym. Eng. Sci., 54(1), 24 (2014)

[24] Kobzar YL, Tkachenko IM, Bliznyuk VN, Shekera OV, Turiv TM, Soroka PV, Nazarenkc VG, Shevchenko VV, Des. Monomers Polym., 19, 1 (2016)

[25] Lim WL, Oo CW, Choo YSL, Looi ST, Polymer, 71, 15 (2015)

[26] Li CH, Chang TC, J. Polym. Sci. A: Polym. Chem., 29, 361 (1991)

[27] Kaya I, Avci A, Temizkan K, Korean J. Chem. Eng., 32(4), 777 (2015)

[28] Marin L, Timpu D, Cozan V, Rusu GI, Airinei A, J. Appl. Polym. Sci., 120(3), 1720 (2011)

[29] Kaya I, Culhaoglu S, Polimery, 54, 266 (2009)

[30] Temizkan K, Ph.D. Thesis, Synthesis, Characterization and Thermal Properties of Polyesters Containing Azomethine Linkage in the Main Chain, Canakkale Onsekiz Mart University, Canakkale, Turkey, 2014.

[31] Gul A, Akhter Z, Siddiq M, Qureshi R, Bhatti AS, J. Appl. Polym. Sci., 131, 8649 (2014)

[32] Kaya I, Dogan F, Gul M, J. Appl. Polym. Sci., 121(6), 3211 (2011)

[33] Marin L, Zabulica A, Sava M, Soft Mater, 11, 32 (2013)

[34] Grucela-Zajac M, Filapek M, Skorka L, Gasiorowski J, Glowacki ED, Neugebauer H, Schab-Balcerzak E, Mater. Chem. Phys., 137(1), 221 (2012)

[35] Potolinca VO, Buruiana E, Oprea S, J. Polym. Res., 20, 1 (2013)

[36] Kaya I, Yıldırım M, Avci A, Synth. Met., 160, 911 (2010)

[37] Kamaci M, Avci A, Kaya I, Prog. Org. Coat., 88, 325 (2015)

[38] Wicks ZW, Jones FN, Pappas SP, in Organic Coatings Science and Technology, Vol. 2, Wiley, New York, 1994, p 116.