Fabrication of free-standing fluorescent mesoporous silica films for detection of nitrobenzene

Fusheng Zhang; Xudong Zheng; Enli Liu; Longbao Yu; Yongsheng Yan

Journal of Industrial and Engineering Chemistry, Vol.46, 397-403, February, 2017

DOI10.1016/j.jiec.2016.11.009 Export Citation

Fabrication of free-standing fluorescent mesoporous silica films for detection of nitrobenzene

Fusheng Zhang, Xudong Zheng, Enli Liu, Longbao Yu, and Yongsheng Yan^†

School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang 212013, PR China

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We report a facile two-step strategy for grafting lanthanide complexes onto the surface of nanocrystalline cellulose-templated mesoporous silica films to prepare luminescence mesoporous silica films, which retain both chiral nematic order of the cellulose nanocrystals and fluorescence of the lanthanide complexes are successfully co-assembled after removal of the cellulose and grafting lanthanide complexes. The films exhibit well-defined fluorescence combining the assembly lanthanide complexes. The mesoporous channels of fluorescent mesoporous silica films are more accessible to the analytes compared with traditional fluorescent materials. So, our fluorescent mesoporous silica films were used as fluorescent sensor for the detection of nitrobenzene.

Keywords:Nanocrystalline cellulose;Fluorescent;Two-step grafting;Silica film

[References]

Akahane Y, Asano T, Song BS, Noda S, Nature, 425, 944 (2003)
Gonzalez-Urbina L, Baert K, Kolaric B, Perez-Moreno J, Clays K, Chem. Rev., 112, 2268 (2011)
Chutinan A, Noda S, Appl. Phys. Lett., 75, 3739 (1999)
Blanco A, Chomski E, Grabtchak S, Ibisate M, John S, Leonard SW, Lopez C, Meseguer F, Miguez H, Mondia JP, Ozin GA, Toader O, van Driel HM, Nature, 405, 437 (2000)
Nguyen TD, Hamad WY, MacLachlan MJ, Adv. Funct. Mater., 24(6), 777 (2014)
Molenkamp WC, Watanabe M, Miyata H, Tolbert SH, J. Am. Chem. Soc., 126(14), 4476 (2004)
Wei H, Lv Y, Han L, Tu B, Zhao D, Chem. Mater., 23, 2353 (2011)
Marlow F, Sharifi P, Brinkmann R, Mendive C, Angew. Chem.-Int. Edit., 48, 6212 (2009)
Waterhouse GI, Chen WT, Chan A, Jin H, Sun-Waterhouse D, Cowie BC, J. Phys. Chem. C, 119, 6647 (2015)
Chen W, Lei W, Xue M, Xue F, Meng ZH, Zhang WB, Qu F, Shea KJ, J. Mater. Chem. A, 2, 7165 (2014)
Arsenault A, Fleischhaker F, von Freymann G, Kitaev V, Miguez H, Mihi A, Tetreault N, Vekris E, Manners I, Aitchison S, Perovic D, Ozin GA, Adv. Mater., 18(20), 2779 (2006)
Braun PV, Rinne SA, Garcia-Santamaria F, Adv. Mater., 18(20), 2665 (2006)
Ju Q, Liu Y, Tu D, Zhu H, Li R, Chen X, Chem.-Eur. J., 17, 8549 (2011)
Liu T, Bai X, Miao C, Dai Q, Xu W, Yu Y, Chen Q, Song H, J. Phys. Chem. C, 118, 3258 (2014)
Abdukayum A, Chen JT, Zhao Q, Yan XP, J. Am. Chem. Soc., 135, 14125 (2013)
Zheng X, Pan J, Gao L, Wei X, Dai J, Shi W, Yan Y, Microchim. Acta, 182, 753 (2014)
Huang P, Zheng W, Zhou S, Tu D, Chen Z, Zhu H, Li R, Ma E, Huang M, Chen X, Angew. Chem.-Int. Edit., 53, 1252 (2014)
Qu X, Yang HK, Moon BK, Choi BC, Jeong JH, Kim KH, J. Phys. Chem. C, 114, 19891 (2010)
Wang Y, Zhu Y, Xu W, Song H, Xu S, Wang J, Cui H, J. Chem. Soc.-Dalton Trans., 42, 14014 (2013)
Kelly JA, Giese M, Shopsowitz KE, Hamad WY, MacLachlan MJ, Acc. Chem. Res., 47, 1088 (2014)
Klemm D, Kramer F, Moritz S, Lindstrom T, Ankerfors M, Gray D, Dorris A, Angew. Chem.-Int. Edit., 50, 5438 (2011)
Habibi Y, Lucia LA, Rojas OJ, Chem. Rev., 110(6), 3479 (2010)
Lin N, Dufresne A, Biomacromolecules, 14(3), 871 (2013)
Cirtiu CM, Dunlop-Briere AF, Moores A, Green Chem., 13, 288 (2011)
Shopsowitz KE, Qi H, Hamad WY, MacLachlan MJ, Nature, 468, 422 (2010)
Florent M, Xue C, Zhao D, Goldfarb D, Chem. Mater., 24, 383 (2012)
Zheng X, Liu E, Zhang F, Yan Y, Pan J, Green Chem., 18, 5031 (2016)
Kelly JA, Shukaliak AM, Cheung CC, Shopsowitz KE, Hamad WY, MacLachlan MJ, Angew. Chem.-Int. Edit., 52, 8912 (2013)
Qu X, Song H, Pan G, Bai X, Dong B, Zhao H, Dai Q, Zhang H, Qin R, Lu S, J. Phys. Chem. C, 113, 5906 (2009)
Qu XS, Dong BA, Pan GH, Bai X, Dai QL, Zhang H, Qin RF, Song HW, Chem. Phys. Lett., 509(1-3), 33 (2011)
Qi H, Shopsowitz KE, Hamad WY, MacLachlan MJ, J. Am. Chem. Soc., 133(11), 3728 (2011)
Qiao XF, Yan B, Inorg. Chem., 48(11), 4714 (2009)
Kelly JA, Yu M, Hamad WY, MacLachlan MJ, Adv. Opt. Mater., 1, 295 (2013)
Mai HX, Zhang YW, Si R, Yan ZG, Sun LD, You LP, Yan CH, J. Am. Chem. Soc., 128(19), 6426 (2006)
Aoki K, Guimard D, Nishioka M, Nomura M, Iwamoto S, Arakawa Y, Nat. Photonics, 2, 688 (2008)
Arsenault A, Clark T, Freymann G, Cademartiri L, Sapienza R, Bertolotti J, Vekris E, Wong S, Kitaev V, Manners I, Nat. Mater., 8, 331 (2009)
Devi P, Reddy P, Arora S, Singh S, Ghanshyam C, Singla M, J. Nanopart. Res., 14, 1 (2012)
Salinas Y, Martinez-Manez R, Marcos MD, Sancenon F, Costero AM, Parra M, Gil S, Chem. Soc. Rev., 41, 1261 (2012)
Zhan C, Ou S, Zou C, Zhao M, Wu CD, Anal. Chem., 86, 6648 (2014)
Beer PD, Gale PA, Angew. Chem.-Int. Edit., 40, 486 (2001)

[Referenced By]

[1] Akahane Y, Asano T, Song BS, Noda S, Nature, 425, 944 (2003)

[2] Gonzalez-Urbina L, Baert K, Kolaric B, Perez-Moreno J, Clays K, Chem. Rev., 112, 2268 (2011)

[3] Chutinan A, Noda S, Appl. Phys. Lett., 75, 3739 (1999)

[4] Blanco A, Chomski E, Grabtchak S, Ibisate M, John S, Leonard SW, Lopez C, Meseguer F, Miguez H, Mondia JP, Ozin GA, Toader O, van Driel HM, Nature, 405, 437 (2000)

[5] Nguyen TD, Hamad WY, MacLachlan MJ, Adv. Funct. Mater., 24(6), 777 (2014)

[6] Molenkamp WC, Watanabe M, Miyata H, Tolbert SH, J. Am. Chem. Soc., 126(14), 4476 (2004)

[7] Wei H, Lv Y, Han L, Tu B, Zhao D, Chem. Mater., 23, 2353 (2011)

[8] Marlow F, Sharifi P, Brinkmann R, Mendive C, Angew. Chem.-Int. Edit., 48, 6212 (2009)

[9] Waterhouse GI, Chen WT, Chan A, Jin H, Sun-Waterhouse D, Cowie BC, J. Phys. Chem. C, 119, 6647 (2015)

[10] Chen W, Lei W, Xue M, Xue F, Meng ZH, Zhang WB, Qu F, Shea KJ, J. Mater. Chem. A, 2, 7165 (2014)

[11] Arsenault A, Fleischhaker F, von Freymann G, Kitaev V, Miguez H, Mihi A, Tetreault N, Vekris E, Manners I, Aitchison S, Perovic D, Ozin GA, Adv. Mater., 18(20), 2779 (2006)

[12] Braun PV, Rinne SA, Garcia-Santamaria F, Adv. Mater., 18(20), 2665 (2006)

[13] Ju Q, Liu Y, Tu D, Zhu H, Li R, Chen X, Chem.-Eur. J., 17, 8549 (2011)

[14] Liu T, Bai X, Miao C, Dai Q, Xu W, Yu Y, Chen Q, Song H, J. Phys. Chem. C, 118, 3258 (2014)

[15] Abdukayum A, Chen JT, Zhao Q, Yan XP, J. Am. Chem. Soc., 135, 14125 (2013)

[16] Zheng X, Pan J, Gao L, Wei X, Dai J, Shi W, Yan Y, Microchim. Acta, 182, 753 (2014)

[17] Huang P, Zheng W, Zhou S, Tu D, Chen Z, Zhu H, Li R, Ma E, Huang M, Chen X, Angew. Chem.-Int. Edit., 53, 1252 (2014)

[18] Qu X, Yang HK, Moon BK, Choi BC, Jeong JH, Kim KH, J. Phys. Chem. C, 114, 19891 (2010)

[19] Wang Y, Zhu Y, Xu W, Song H, Xu S, Wang J, Cui H, J. Chem. Soc.-Dalton Trans., 42, 14014 (2013)

[20] Kelly JA, Giese M, Shopsowitz KE, Hamad WY, MacLachlan MJ, Acc. Chem. Res., 47, 1088 (2014)

[21] Klemm D, Kramer F, Moritz S, Lindstrom T, Ankerfors M, Gray D, Dorris A, Angew. Chem.-Int. Edit., 50, 5438 (2011)

[22] Habibi Y, Lucia LA, Rojas OJ, Chem. Rev., 110(6), 3479 (2010)

[23] Lin N, Dufresne A, Biomacromolecules, 14(3), 871 (2013)

[24] Cirtiu CM, Dunlop-Briere AF, Moores A, Green Chem., 13, 288 (2011)

[25] Shopsowitz KE, Qi H, Hamad WY, MacLachlan MJ, Nature, 468, 422 (2010)

[26] Florent M, Xue C, Zhao D, Goldfarb D, Chem. Mater., 24, 383 (2012)

[27] Zheng X, Liu E, Zhang F, Yan Y, Pan J, Green Chem., 18, 5031 (2016)

[28] Kelly JA, Shukaliak AM, Cheung CC, Shopsowitz KE, Hamad WY, MacLachlan MJ, Angew. Chem.-Int. Edit., 52, 8912 (2013)

[29] Qu X, Song H, Pan G, Bai X, Dong B, Zhao H, Dai Q, Zhang H, Qin R, Lu S, J. Phys. Chem. C, 113, 5906 (2009)

[30] Qu XS, Dong BA, Pan GH, Bai X, Dai QL, Zhang H, Qin RF, Song HW, Chem. Phys. Lett., 509(1-3), 33 (2011)

[31] Qi H, Shopsowitz KE, Hamad WY, MacLachlan MJ, J. Am. Chem. Soc., 133(11), 3728 (2011)

[32] Qiao XF, Yan B, Inorg. Chem., 48(11), 4714 (2009)

[33] Kelly JA, Yu M, Hamad WY, MacLachlan MJ, Adv. Opt. Mater., 1, 295 (2013)

[34] Mai HX, Zhang YW, Si R, Yan ZG, Sun LD, You LP, Yan CH, J. Am. Chem. Soc., 128(19), 6426 (2006)

[35] Aoki K, Guimard D, Nishioka M, Nomura M, Iwamoto S, Arakawa Y, Nat. Photonics, 2, 688 (2008)

[36] Arsenault A, Clark T, Freymann G, Cademartiri L, Sapienza R, Bertolotti J, Vekris E, Wong S, Kitaev V, Manners I, Nat. Mater., 8, 331 (2009)

[37] Devi P, Reddy P, Arora S, Singh S, Ghanshyam C, Singla M, J. Nanopart. Res., 14, 1 (2012)

[38] Salinas Y, Martinez-Manez R, Marcos MD, Sancenon F, Costero AM, Parra M, Gil S, Chem. Soc. Rev., 41, 1261 (2012)

[39] Zhan C, Ou S, Zou C, Zhao M, Wu CD, Anal. Chem., 86, 6648 (2014)

[40] Beer PD, Gale PA, Angew. Chem.-Int. Edit., 40, 486 (2001)