화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.46, 426-435, February, 2017
DOI10.1016/j.jiec.2016.11.013  Export Citation
Stearic acid hydrodeoxygenation over Pd nanoparticles embedded in mesoporous hypercrosslinked polystyrene
Valentin N. Sapunov, Antonina A. Stepacheva1, †, Esther M. Sulman1, Johan Wärna2, Päivi Mäki-Arvela2, Mikhail G. Sulman1, Alexander I. Sidorov1, Barry D. Stein3, Dmitry Yu. Murzin2, and Valentina G. Matveeva1
  • D. Mendeleyev University of Chemical Technology of Russia, Miusskaya sq. 9, 125047 Moscow, Russia, Russian Federation
  • 1Tver State Technical University, A. Nikitin Street 22, 170026 Tver, Russia, Russian Federation
  • 2Åbo Akademi University, Process Chemistry Centre, FI-20500 Turku/Åbo, Finland
  • 3Department of Biology, Indiana University, Jordan Hall, 1001 East Third Street, 47405-7005 Bloomington, IN, USA
E-mail:
Stearic acid hydrodeoxygenation into n-heptadecane on the catalyst containing Pd nanoparticles incorporated in the hypercrosslinked polystyrene matrix was studied. The used catalysts were characterized using TEM, CO chemisorption, low-temperature nitrogen physisorption and XPS. A clear hydrogen pressure dependent induction period was noticed. Kinetic regularities were studied for the indicated reaction in the presence of polymer based catalysts. A mathematical model for decarboxylation was suggested which was able to adequately describe experimental data at different temperatures, hydrogen pressures and initial concentrations of stearic acid. Kinetic constants were calculated and their statistical analysis was performed.
Keywords:Stearic acid;Hydrodeoxygenation;Hypercrosslinked polystyrene;Kinetics
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