화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.34, No.3, 600-608, March, 2017
DOI10.1007/s11814-016-0365-2  Export Citation
Facile synthesis of imprinted submicroparticles blend polyvinylidene fluoride membranes at ambient temperature for selective adsorption of methyl p-hydroxybenzoate
Yanhua Cui, Minjia Meng, Dongshu Sun, Yan Liu, Jianming Pan, Xiaohui Dai, and Yongsheng Yan†
  • School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China
E-mail:
We developed a simple phase inversion technique to prepare molecularly imprinted membrane (MIM) at room temperature for membrane selective adsorption and separation of methyl p-hydroxybenzoate (M4HB). The prepared SMIP-MIM was characterized by SEM, FT-IR, TGA. Compared with non-imprinted membrane (NIM1-5) adsorbent, SMIP-MIM1-5 adsorbent with high specific surface area and showed higher binding capacity, faster kinetic and better selectively adsorption capacity for M4HB. The maximum isotherm adsorption capacity for M4HB of SMIPMIM4 was 3.519mg·g-1, and the experimental data was well fitted to the slips model by multiple analysis. The maximum kinetic adsorption capacity and equilibrium adsorption time for SMIP-MIM4 were 1.335mg·g-1 and 160 min, respectively. The mechanism for dynamic adsorption of M4HB onto SMIP-MIM4 was found to follow pseudo-firstorder model and pseudo-second-order model. Additionally, the permeability separation factor of SMIP-MIM4 for M4HB compared to a structural analogues methyl 2-hydroxybenzoate (M2HB) could reach 2.847. The adsorption capacity of SMIP-MIM4 for M4HB and M2HB was 0.549mg·cm.2 and 1.563mg·cm-2, respectively. The adsorption behavior of M4HB through SMIP-MIM4 followed the retarded permeation mechanism.
Keywords:Methyl p-Hydroxybenzoate;Molecular Imprinted Membranes;Selective Adsorption;Phase Inversion Technique
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