The room temperature properties of aqueous solutions of SPC, TIP4P, and MCY water are examined using either a potential cutoff or Ewald summation. The effects of interaction truncation are compared to the importance of the medium (vacuum or metal) that the entire system is immersed in; for this purpose simulations an also carried out in which the unit cell surface polarization term of De Leeuw, Perram, and Smith (Proc. R. Soc. London 1980, A373, 27) is explicitly accounted for. Both pure water and dilute solutions of Cl- and Fe2+ are investigated. It is found that not only solvent-solvent orientational correlations but also ion-solvent energies, ion-induced solvent reorganization energies, and ionic diffusion coefficients can be exceedingly sensitive to the nature of the surroundings. It is asserted that reaction field methods and Ewald summation are the preferred types of boundary conditions, but that the method of parametrization of the potential functions has to be consistent with the eventual simulation conditions.