We rationally designed a new type of hybrid materials, molybdenum disulfide (MoS2) synthesized by Mo pre-deposition followed by subsequent sulfurization process directly on thermal chemical vapor deposition (TCVD)-grown graphene, for applications in a multifunctional device. The synthesis of stoichiometric and uniform multilayer MoS2 and high-crystalline monolayer graphene was evaluated by X-ray photoelectron spectroscopy and Raman spectroscopy. To examine the electrical transport and photoelectrical properties of MoS2-graphene hybrid films, field effect transistors (FETs) and visible-light photodetectors based on MoS2-graphene were both fabricated. As a result, the extracted mobility for MoS2-graphene hybrid FETs was two times higher than that of MoS2 FETs. In addition, the MoS2-graphene photodetectors revealed a significant photocurrent with abrupt switching behavior under periodic illumination. (C) 2016 Elsevier B.V. All rights reserved.