Catalysis Today, Vol.279, 317-326, 2017
Conversion of glycerol into lactic acid using Pd or Pt supported on carbon as catalyst
The oxidation of glycerol into lactic acid using activated carbon with Pd or Pt as heterogeneous catalysts was study. Several reaction parameters were evaluated: catalyst loading, catalyst weight, NaOH/glycerol molar ratio, temperature and reaction time. The textural and structural properties of the carbon supported catalysts (fresh and spent) were evaluated by N-2 adsorption-desorption isotherms at -196 degrees C, XRD, SEM, EDX, TEM and XPS. It was possible to achieve a glycerol conversion of about 99% with selectivity to lactic acid of 68% and 74% using 10% Pd/C and 5% Pt/C as catalysts, respectively, at 230 degrees C of reaction temperature. Moreover, Pd/C and Pt/C catalysts were used in five reaction cycles without significant loss of activity, highlighting the great stability of the prepared catalysts. (C) 2016 Elsevier B.V. All rights reserved.