In China, coal, often with a high level of sulfur, is always mixed with municipal solid waste (MSW) in waste incineration plants due to the low heating value and high moisture content of MSW. The influence of sulfur compounds on the volatilization of heavy metals in MSW is of great concern for China's waste incineration plants. In this study, the continuous dynamic volatilization process of Pb and Cd is investigated by adding different forms of sulfur compounds, elemental sulfur (S), and sodium sulfate (Na2SO4), to the simulated MSW in a laboratory incinerator, at both 1 and 3 wt %, respectively. The experimental results show that the added S begins to affect the volatilization of Pb and Cd at about 700 degrees C; adding S can lead up to 49.6% reduction in the volatilization of Pb, as the produced sulfur dioxide is promoting the formation of a condensed sulfate phase, and part of Pb is fixed, in the form of PbS in the bottom ash. But for Cd, adding S causes up to 15.9% increase in its volatilization as S seizes part of 02 in the air, which is conducive to forming the reducing atmosphere. In the reducing atmosphere, CdO can be easily reduced to Cd, which volatilizes more easily than CdO at high temperatures. In fact, in the reducing atmosphere, the volatilization of Cd far outweighs the volatilization of Pb at 700-800 degrees C. On the other hand, adding Na2SO4 almost has no influence on the volatilization of lead and cadmium below 900 degrees C.