Abundant waste from ladle furnace (LF) steel slag industry was utilized to catalyze the glycerol transesterification reaction with dimethyl carbonate (DMC) to synthesize valuable glycerol carbonate (GC). LF slag was modified using various sodium hydroxide (NaOH) loadings (1-15 wt.%), and the Catalyst samples were characterized using XRD, FTIR, TPD-CO2, and EDS techniques, Modifying the LF using different NaOH loadings enhanced the stability, basicity, and basic strength of LF. Favorable reaction conditions at the best glycerol conversion and GC yield were investigated via reaction influencing parameter screening. Thus, the 10 wt.% NaOH incorporated in LF under the reaction conditions of 75 degrees C, DMC-to-glycerol molar ratio of 2, and 3 wt.% catalyst dosage achieved 99% glycerol conversion and 97% GC yield. The catalyst exhibited sufficient heterogeneity and was utilized in five successive cycles of the experiment without serious deactivation. (C) 2016 Elsevier Ltd. All rights reserved.