Vitrinite-rich concentrates were produced using a float-sink technique from five single-rank Chinese bituminous coals with R-random ranging from 0.88% to 1.73%. The non-isothermal thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) of these concentrates were carried out simultaneously at the heating rate of 8 degrees C/min from 50 degrees C to 1200 degrees C, and the determination of the caking index (G) was also performed. The TGA results demonstrate that the devolatilization is divided into three regions and there are not explicit relationships between coal rank and characteristic parameters during the 300-900 degrees C region, such as DTG(max), T-max, and weight loss. The DSC results show that the heat of pyrolysis is comprised of three stages characterized by different heat flows and no explicit correlations between coal rank and heat flow as well as peak number in the range of 300-900 degrees C exist. In terms of the TGA and DSC results, the relationship between the caking index and characteristic parameters derived from the TGA and DSC curves is examined and developed to predict the caking index of single-rank bituminous coal. (C) 2016 Elsevier B.V. All rights reserved.