The structures and CO binding energies are computed for Fe(CO)(n)(-) using a hybrid density functional theory (DFT) approach. The structures and ground states can be explained in terms of maximizing the Fe to CO 2 pi* donation and minimizing Fe-CO 5 sigma repulsion. The trends in the CO binding energies for Fe(CO)(n)(-) and the differences between the trends for Fe(CO)(n)(-) and Fe(CO)(n) are also explained. For Fe(CO)(n)(-), the second, third, and fourth CO bonding energies are in good agreement with experiment, while the first is too small. The first CO binding is also too small using the coupled cluster singles and doubles approach including a perturbational estimate of the connected triple excitations.