Formation, Characterization, and Reactivity of a Nonheme Oxoiron(IV) Complex Derived from the Chiral Pentadentate Ligand asN4Py

Lakk-Bogath D; Csonka R; Speier G; Reglier M; Simaan AJ; Naubron JV; Giorgi M; Lazar K; Kaizer J

Inorganic Chemistry, Vol.55, No.20, 10090-10093, 2016

DOI10.1021/acs.inorgchem.6b01089 Export Citation

Formation, Characterization, and Reactivity of a Nonheme Oxoiron(IV) Complex Derived from the Chiral Pentadentate Ligand asN4Py

Lakk-Bogath D, Csonka R, Speier G, Reglier M, Simaan AJ, Naubron JV, Giorgi M, Lazar K, Kaizer J

The chiral pentadentate low-spin (S = 1) oxoiron(IV) complex [Fe-IV(O)(asN4Py)](2+) (2) was synthesized and spectroscopically characterized. Its formation kinetics, reactivity, and (enantio)selectivity in an oxygen-atom-transfer reaction was investigated in detail and compared to a similar pentadentate ligand-containing system.