Journal of Crystal Growth, Vol.456, 67-72, 2016
A new system for sodium flux growth of bulk GaN. Part II: in situ investigation of growth processes
We report recent results of bulk GaN crystal growth using the sodium flux method in a new crucible-free growth system. We observed a (0001) Ga face (+c-plane) growth rate > 50 mu m/h for growth at a N-2 overpressure of 5 MPa and 860 degrees C, which is the highest crystal growth rate reported for this technique to date. Omega X-ray rocking curve (omega-XRC) measurements indicated the presence of multiple grains, though full width at half maximum (FWHM) values for individual peaks were < 100 arcseconds. Oxygen impurity concentrations as measured by secondary ion mass spectroscopy (SIMS) were > 10(20) atoms/cm(3). By monitoring the nitrogen pressure decay over the course of the crystal growth, we developed an in situ method that correlates gas phase changes with precipitation of GaN from the sodium-gallium melt. Based on this analysis, the growth rate may have actually been as high as 90 mu m/h, as it would suggest GaN growth ceased prior to the end of the run. We also observed gas phase behavior identified as likely characteristic of GaN polynucleation. (C) 2016 Elsevier B.V. All rights reserved.
Keywords:Na flux method;Growth rate;Growth from high temperature solutions;Sodium flux growth;Nitrides;III-Nitrides;Bulk GaN