화학공학소재연구정보센터
Journal of Electroanalytical Chemistry, Vol.784, 13-24, 2017
Change in the physical characteristics of the dendritic zinc deposits in the stationary and pulsating electrolysis
The growth process of dendritic zinc deposits is investigated on rod electrode in stationary and pulsating modes of electrolysis in this study. The data on changes in physical properties (density, porosity, and specific surface area) of loose deposits in the electrolysis process are obtained. It is found that during the pauses of pulsating modes, duration of which was 15 and 30 s, there is an increase in the discharging ions concentration in the deposit depth. The change in concentration in pulsating galvanostatic mode is due to diffusion, whereas in potentiostatic mode it is due to the dissolution of dendrites in contact with the depleted solution. The decrease in the diffusion limitations leads to a decrease in the deposits elongation rate and an increase in its density. The SEM method shows that the transition from stationary to pulsating modes of electrolysis changes the loose deposit particles morphology. (C) 2016 Elsevier B.V. All rights reserved.