Journal of Hazardous Materials, Vol.321, 517-527, 2017
Degradation of tricyclazole: Effect of moisture, soil type, elevated carbon dioxide and Blue Green Algae (BGA)
Pesticide persistence and degradation in soil are influenced by factors like soil characteristics, light, moisture etc. Persistence of tricyclazole was studied under different soil moisture regimes viz., dry, field capacity and submerged in two different soil types viz., Inceptisol and Ultisol from Delhi and Karnataka, respectively. Tricyclazole dissipated faster in submerged (t1 /2 160.22-177.05 d) followed by field capacity (t1/2 167.17-188.07 d) and dry (tl /2 300.91-334.35 d) in both the soil types. Half-life of tricyclazole in Delhi field capacity soil amended with Blue Green Algae (BGA), was 150.5 d as compared to 167.1 d in unamended soil. In Karnataka soil amended with BGA the half-lives were 177.0 d compared to 188.0 d in unamended soil, indicating that BGA amendment enhanced the rate of dissipation of in both the selected soils. Tricyclazole was found to be stable in water over a pH range of 3-9, the half life in paddy field was 60.20 d and 5.47 din paddy soil and paddy water, respectively. Statistical analysis and Duncan's Multiple Range Test (DMRT) revealed significant effect of moisture regime, organic matter and atmospheric CO2 level on dissipation of tricyclazole from soil and pH of water (at 95% confidence level p <0.0001). (C) 2016 Elsevier B.V. All rights reserved.
Keywords:Blue Green Algae (BGA);Dissipation;Elevated CO2;High performance liquid chromatography (HPLC);Tricyclazole