Journal of Polymer Science Part B: Polymer Physics, Vol.55, No.2, 189-197, 2017
The Effect of a Semi-Industrial Masterbatch Process on the Carbon Nanotube Agglomerates and Its Influence in the Properties of Thermoplastic Carbon Nanotube Composites
This study details an industrial process to prepare polypropylene (PP) composites reinforced with different loadings (0.5-10wt.%) of carbon nanotubes (CNTs) from a direct dilution of a masterbatch produced by an optimized extrusion compounding process. The work demonstrates how the anisotropy in the distribution of CNTs can have a positive effect on the electrical conductivity and fracture toughness of the resulting composites. The composite with the highest loading of CNTs had an electrical conductivity of 10(-2) S/m comparable with those reported in the available literature. The composites showed anisotropy in their properties that seems to be caused by the non-homogeneous distribution of the agglomerates produced by the orientation of the flow direction during the injection process. The composites produced in this work exhibited a fracture toughness up to 55% higher than neat PP and failed by polymer ductile tearing. It was found that the CNT agglomerates distributed throughout the matrix increased the toughness of PP by promoting plastic deformation of the matrix during the fracture process and by a slight load transfer between the polymer matrix and the CNTs of the agglomerates. (C) 2016 Wiley Periodicals, Inc.
Keywords:anisotropy;carbon nanotubes;electrical conductivity;fracture toughness;polymer-matrix composites