Novel polymers with styrylquinoline moiety and different substituents units are presented. Styrylquinoline polymers were obtained by a three-step synthetic approach. This includes the condensation, preparation of a methacrylic monomers and their polymerization. Their photophysical and photochemical properties have been investigated. Polymers were characterized by (HNMR)-H-1, UV spectroscopy and GPC, DSC techniques. The synthesized polymers exhibited glass transition temperatures in the range of 153-184 degrees C.