Journal of Physical Chemistry, Vol.99, No.33, 12387-12390, 1995
Quantum-Mechanical Theory of Collisional Recombination Rates
Quantum mechanical expressions for the pressure-dependent recombination rate (within the strong collision assumption) are presented which have a very similar form to those developed recently for rate constants of chemical reactions : eqs 11 and 12 express the recombination rate in terms of a flux autocorrelation function, and eqs 14-16 in terms of a cumulative recombination probability. The qualitative behavior of these functions is illustrated by several pedagogical examples.
Keywords:THERMAL RATE CONSTANTS;FLUX CORRELATION-FUNCTIONS;DISCRETE VARIABLE REPRESENTATION;CUMULATIVE REACTION PROBABILITY;RATE COEFFICIENTS;STABILIZATION;DISSOCIATION;DYNAMICS