Ion/molecule imprinted polymers with double binding sites via twice imprinting strategy for selective and simultaneous removal of λ-cyhalothrin and Cu(II)

Hengjia Zhu; Jianming Pan; Jun Cao; Yue Ma; Fengxian Qiu; Wenli Zhang; Yongsheng Yan

Journal of Industrial and Engineering Chemistry, Vol.49, 198-207, May, 2017

DOI10.1016/j.jiec.2017.01.028 Export Citation

Ion/molecule imprinted polymers with double binding sites via twice imprinting strategy for selective and simultaneous removal of λ-cyhalothrin and Cu(II)

Hengjia Zhu, Jianming Pan^†, Jun Cao¹, Yue Ma, Fengxian Qiu^†, Wenli Zhang, and Yongsheng Yan

School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China
¹Yancheng Entry-Exit Inspection and Quarantine Bureau, China

E-mail:,

Herein we reported a facile method to prepare porous ion/molecule imprinted polymers (I-MIPs) via twice imprinting strategy for the simultaneous uptake of copper ions (Cu(II)) and λ-cyhalothrin (LC). Firstly, N-(β-aminoethyl)-Υ-aminopropytrimethoxysilane (DAMO) was grafted on silica particles surface to synthesis Cu(II)-imprinted polymers to introduce iron imprinted sites. They were then utilized as stabilizers to prepare a stable W/O Pickering HIPEs template (LC as the imprinting molecule), which was then polymerized with dual imprinting sites including Cu(II) and LC. The adsorption equilibrium, kinetic results and selective recognition experiments were exhibited their prospected dual selectivity and simultaneous removal of LC and Cu(II).

Keywords:Ion/molecule imprinted polymers;λ-Cyhalothrin molecules;Copper ions;Simultaneous removal;Twice imprinting strategy

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[1] Yang JS, Ren HB, Xie YJ, Biomacromolecules, 12(8), 2982 (2011)

[2] Ericksson P, Talts U, Neurotoxicology, 21, 37 (2000)

[3] Shafer TJ, Meyer DA, Crofton KM, Environ. Health Perspect., 113, 123 (2005)

[4] Liu Huan, Kong Delong, Sun Wei, Li Qunsheng, Zhou Zhiyong, Ren Zhongqi, Chem. Eng. J., 303, 348 (2016)

[5] Zhan YC, Luo XB, Nie SS, Huang YN, Tu XM, Luo SL, Ind. Eng. Chem. Res., 50(10), 6355 (2011)

[6] Jeong EY, Ansari MB, Mo YH, Park SE, J. Hazard. Mater., 185(2-3), 1311 (2011)

[7] Wei KQ, Yang JX, Ecotox. Environ. Safe., 113, 446 (2015)

[8] Malachova K, Rybkova Z, Sezimova H, Cerven J, Water Res., 47, 7143 (2013)

[9] Bellas J, Vazquez E, Beiras R, Water Res., 35, 2905 (2001)

[10] Vinu R, Madras G, Environ. Sci. Technol., 43, 473 (2009)

[11] Salima A, Benaouda B, Noureddine B, Duclaux L, Water Res., 47, 3375 (2013)

[12] Zhang TL, Yue XD, Zhang KR, Lia JH, Zhu CY, Zhang L, Chen W, Mater. Des., 107, 372 (2016)

[13] Zhu WJ, Ma W, Li CX, Pan JM, Dai XH, Chem. Eng. J., 276, 249 (2015)

[14] Jiang W, Wang WF, Pan BC, Zhang QX, Zhang WM, Lv L, ACS Appl. Mater. Interfaces, 6, 3421 (2014)

[15] Chen XX, Chen BL, Environ. Sci. Technol., 49, 6181 (2015)

[16] Pan JM, Zeng J, Cao Q, Gao HP, Gen YC, Peng YX, Dai XH, Yan YS, Chem. Eng. J., 284, 1361 (2016)

[17] Chen L, Ji T, Brisbin L, Zhu JH, ACS Appl. Mater. Interfaces, 7, 12230 (2015)

[18] Qi PF, Pichler T, Langmuir, 30(37), 11110 (2014)

[19] Venkatesh A, Chopra N, Krupadam RJ, Environ. Sci. Pollut. Res., 21, 6603 (2014)

[20] Wulf G, Sarhan A, Angew. Chem.-Int. Edit., 11, 341 (1972)

[21] Vlatakis G, Andersson LI, Miller R, Mosbach K, Nature, 361, 645 (1993)

[22] Liu JQ, Wulff G, J. Am. Chem. Soc., 126(24), 7452 (2004)

[23] Gan MY, Pan JM, Zhang YL, Dai XH, Yin YJ, Qu Q, Yan YS, Chem. Eng. J., 257, 317 (2014)

[24] Monier M, Ibrahim AA, Metwally MM, Badawy DS, Int. J. Biol. Macromol., 81, 736 (2015)

[25] Hu YQ, Yin SW, Zhu JH, Food Hydrocoll., 61, 300 (2016)

[26] Pan JM, Zeng J, Cao Q, Gao HP, Chem. Eng. J., 84, 1361 (2016)

[27] Pulko I, Wall J, Krajnc P, Cameron NR, Chem. Eur. J., 16, 2350 (2010)

[28] Cameron NR, Polymer, 46(5), 1439 (2005)

[29] Yin YJ, Pan JM, Cao J, Ma Y, Pan GQ, Wu RR, Dai XH, Meng MJ, Yan YS, Chem. Eng. J., 286, 485 (2016)

[30] Stober W, Fink A, Bohn E, J. Colloid Interface Sci., 26, 62 (1968)

[31] Pan JM, Qu Q, Cao J, Yan D, Liu JX, Dai XH, Yan YS, Chem. Eng. J., 253, 138 (2014)

[32] Gao HP, Pan JM, Han DL, Zhang YL, Shi WD, Zeng J, Peng YX, Yan YS, J. Mater. Chem., A3, 13507 (2015)

[33] Menner A, Biamarck A, Macromol. Symp., 242, 19 (2006)

[34] Lu YK, Yan XP, Anal. Chem., 76, 453 (2004)

[35] Fan HT, Fan XL, Li J, Guo MM, Zhang DS, Yan F, Sun T, Ind. Eng. Chem. Res., 51(14), 5216 (2012)

[36] Hou HB, Yu DM, Hu GH, Langmuir, 31(4), 1376 (2015)

[37] Zhao JQ, Lu CH, He X, Zhang XF, Zhang W, Zhang XM, ACS Appl. Mater. Interfaces, 7, 2607 (2015)

[38] Egodawatte S, Datt A, Burns EA, Larsen SC, Langmuir, 31(27), 7553 (2015)

[39] Ghodbane I, Hamdaoui O, J. Hazard. Mater., 160(2-3), 301 (2008)

[40] Ariya PA, Amyot M, Dastoor A, Deeds D, Feinberg A, Kos G, Poulain A, Ryjkov A, Semeniuk K, Subir M, Toyota K, Chem. Rev., 115(10), 3760 (2015)

[41] Liu Q, Zhong LB, Zhao QB, Frear C, Zheng YM, ACS Appl. Mater. Interfaces, 7, 14573 (2015)

[42] Oh Y, Le VD, Maiti UN, Hwang JO, Park WJ, Lim J, Lee KE, Bae YS, Kim YH, Kim SO, ACS Nano, 9, 9148 (2015)

[43] Birlik E, Ersoz A, Acikkalp E, Denizli A, Say R, J. Hazard. Mater., 140(1-2), 110 (2007)

[44] Pan JM, Zeng J, Cao Q, Gao HP, Gen YC, Peng YX, Dai XH, Yan YS, Chem. Eng. J., 284, 1361 (2016)