Experimental flame characterization is necessary for the development and validation of chemical kinetics models. Low temperature oxidation produces a cool flame, which is a combustion phenomenon resulting from negative temperature coefficient (NTC) behavior. Kinematic stabilization of premixed, freely propagating, ozone-activated, cool flames of dimethyl ether (DME) has been investigated at sub-atmospheric pressure of 7.3 kPa using a laminar flat flame Hencken burner. This platform permits estimation of laminar propagation speed, as well as spatially-resolved temperature and species mole fractions along the burner axis. Stability mapping for a range of equivalence ratios (phi) was performed to determine the range of ozone concentrations for which a cool flame can be sustained. Based on the results of stability mapping, an ozone concentration of 6.1% in oxygen was chosen to investigate the characteristics of DME cool flames over a range of equivalence ratios from phi = 0.4 to 1.4. Two distinct cool flame stabilization modes were observed in experiments: a burner-stabilized mode at low reactant flow rates, and a freely propagating mode at higher flow rates. From the transition between the two modes, cool flame propagation speeds from phi = 0.4 to 1.4 were determined. Flame temperatures were measured at these equivalence ratios, with maximum temperatures decreasing from 885 K at phi = 0.4 to 779 K at phi = 1.4. A single equivalence ratio of phi = 0.6 was chosen for detailed investigation of the flame structure, including spatial measurements of temperature and species as a function of height above the burner. Experimental results were compared to numerical simulations of a phi = 0.6 cool flame. Experimental propagation speed was found to be within 25% of the numerical value, and significant agreement between experimental and numerical species profiles was observed. (C) 2016 The Combustion Institute. Published by Elsevier Inc. All rights reserved.