Mo-doped Pr0.6Sr0.4Fe0.8Ni0.2O3-delta(PSFNM) perovskites are synthesized by a modified Pechini method and evaluated as both anode and cathode for intermediate -temperature symmetrical solid oxide fuel cell (SSOFC). The influence of Mo-doping on structure, conductivity, thermal expansion coefficient and electrochemical performance of Pr0.6Sr0.4Fe0.8Ni0.2O3-delta (PSFN) electrode are investigated. The results indicate that PSFNM exhibits a cubic perovskite structure and shows a good reversibility. After heated at 800 degrees C for 10 h in humidified H-2, some new phases of SrPrFeO4, Pr2O3, and Fe-Ni alloy in PSFNM are identified by powder X-ray diffraction analysis. Although the conductivity of Mo-doped sample is slightly decreased, the thermal expansion compatibility and hydrogen oxidation reaction (HOR) activity are gradually improved. The maximum power density of SSOFC increase from 435 mW/cm(2) to 500 mW/cm(2) at 800 degrees C, and the corresponding polarization resistance decrease from 0.102 Omega.cm(2) to 0.070 Omega.cm(2), respectively. In addition, the SSOFC with PSFNM electrode shows a robust stability after operating at 700 degrees C for 100 h. These results demonstrate that PSFNM is a promising electrode for SSOFC at intermediate temperatures. (C) 2016 Elsevier Ltd. All rights reserved.