화학공학소재연구정보센터
Heat Transfer Engineering, Vol.38, No.13, 1189-1197, 2017
Heat Transfer Modeling of a Charring Material Using Isoconversional Kinetics
An isoconversional modeling approach has been considered in the modeling of heat transfer and pyrolysis in a charring material. The isoconversional approach is appealing due to the use of only a single reacting component as opposed to the multi-component model typically used. This reduces the number of required field variables which reduces numerical demands in large multi-dimensional models. In this study, isoconversional parameters have been reduced from available test data for a generic ablative material. The results were evaluated by implementing the approach into a 1-D ablation heat transfer program and modeling the thermal and decomposition response of a charring material subjected to an elevated surface temperature. The results were compared to the same modeling using a traditional multi-component Arrhenius approach. Modeling outputs showed that the twomethods produced very similar results when proper care was taken in the tabulated parameters of the isoconversional model which is susceptible to variations in supporting test data and is sensitive to table resolution. The results of this study indicate that the isoconversional model provides a viable alternative to the widely used multi-component approach.