화학공학소재연구정보센터
Journal of Physical Chemistry, Vol.100, No.4, 1246-1255, 1996
Brownian Dynamics Derivation of the Association Formulation for the Conductance Equations
From the bases of statistical mechanics a conductance equation is obtained which includes the Bjerrum association concept without making use of any ad hoc chemical model. The Hamiltonian model used is general enough to permit the a posteriori introduction of more specific Gurney cosphere ionic interactions. The former analytical results of Fuoss-Onsager and Falkenhagen et al. become a limit case formulation of the restricted primitive model applied to ions of lower electronic charges in solvents in higher dielectric constants.