화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.42, No.5, 2904-2913, 2017
Energy conservative brown coal conversion to hydrogen and power based on enhanced process integration: Integrated drying, coal direct chemical looping, combined cycle and hydrogenation
An integrated system for converting brown coal to H-2 and power is proposed. This system consists of coal drying, coal direct chemical looping, combined cycle, and hydrogenation. The energy involved in each module is recirculated thoroughly before it is integrated with the other modules, meaning that any unrecoverable energy can be utilized in other modules. In coal direct chemical looping, three continuous reactions are employed, namely, reduction, oxidation, and combustion. Iron oxide is used here as the oxygen carrier that is recirculated among the reactors. Toluene is adopted as the organic carrier in the hydrogenation process, reacting with H-2 to produce methylcyclohexane. We evaluated the performance of the system through a selection of operating conditions. The effect of the carbon conversion efficiency during the reduction was also clarified. The proposed system achieved high values for the production of H-2 and power generation efficiencies, which are 71.4% and 19.9%, respectively. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.