The study presents p-T-x-y phase equilibria measurements of an oxygenated compound (furan) and one of its potential solvents of extraction (toluene). The experimental technique of the equipment recently developed is based on a static analytic method. Measurements were done at 3 temperatures (313.02, 333.02, and 352.99 K) and pressures from 13 to 375 kPa. The experimental data measured were successfully correlated using a gamma-phi approach with the nonrandom two-liquid activity coefficient model.