Journal of the American Ceramic Society, Vol.100, No.4, 1697-1706, 2017
Low-temperature synthesis of nanocrystalline hydroxyapatite: Effect of Mg and Sr content
Nanocrystalline Mg- or Sr-containing hydroxyapatite powders were synthesized through low-temperature chemical precipitation. The most significant factor for reduction in particle sizes included adjusting the reaction temperature between 0 degrees C and 50 degrees C. Syntheses products were characterized using several analytical tools to determine purity and influence of added amount (up to 15mol%) of Mg or Sr on the composition and structure. Qualitative analysis by Fourier transform infrared spectroscopy and low intensity, broad X-ray diffraction peaks indicated the presence of nanocrystalline and/or amorphous hydroxyapatite in all the products. Moreover, a significant decrease in the crystallinity was observed with increasing Mg (up to 2.8 +/- 0.3wt%) and Sr (up to 9.6 +/- 1.0wt%) concentration. N-2 adsorption and scanning electron microscopy characterizations confirmed the nanocrystalline nature of the synthesized products. The synthesized products had nanosized spherical-like particle morphology with the specific surface area ranging from 89 +/- 7 to 150 +/- 20m(2)/g.