화학공학소재연구정보센터
Polymer, Vol.112, 414-417, 2017
The swelling of weak polyelectrolytes at low salt concentrations in dilute solution
The possibility of swelling of single polyelectrolyte chains in dilute aqueous solution by free ions in the presence of a small amount of salt is investigated using a mean-field approach. The swelling of chains by free ions is more likely for larger chains in solutions containing only a small amount of salt. The swollen chains are likely to retain a spherical structure. (C) 2017 The Author. Published by Elsevier Ltd. This is an open access article under the CC BY license