Fine particles from industrial processes are considered to be potentially harmful to humans and environment, and massive amounts of fine particles are continuously emitted into the air due to the low removal efficiency of current conventional dust capture devices. A novel pretreatment process using the coupling effect of pulsed corona discharge and acoustic waves enhanced by spray droplets for fine particle agglomeration and capture was investigated in this study. The application of pulsed corona discharge in an acoustic field led to an increase in the efficiency of fine particle agglomeration to 74.7%, and the improvement was much more obvious for low frequency acoustic waves. The spray flow rate delivered by the spray nozzles with a size of 0.30 mm or 0.40 mm was incrementally increased. Furthermore, the penetration efficiency initially decreased, then increased, and finally decreased when droplets were sprayed in either a pulsed corona discharge field or an acoustic wave field. The penetration efficiency of fine particles substantially decreased to 10% with the enhancement of spray droplets coupled with both a pulsed corona discharge and an acoustic wave, both at their most efficient settings. The penetration efficiency further decreased with the addition of sodium dodecyl sulfonic salt surfactant to the spray droplets, in particular, at a concentration of 0.3%. (C) 2017 Elsevier B.V. All rights reserved.