화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.50, 1-14, June, 2017
DOI10.1016/j.jiec.2017.01.032  Export Citation
Vitreous and crystalline phosphate high level waste matrices: Present status and future challenges
Ashish Bohre†, Kalpana Avasthi1, and Vladimir I. Pet’kov2
  • Department of Chemistry, University of Delhi, North Campus, Delhi 110 007, India
  • 1Department of Chemistry, Dr. H. S. Gour Central University, Sagar 470 003, India
  • 2Department of Chemistry, Lobachevsky State University of Nizhniy Novgorod, Pr. Gagarina 23, Nizhniy Novgorod 603950, Russia, Russian Federation
E-mail:
Vitrification is currently the most effective process for immobilization of nuclear waste. However, ubiquitous borosilicate glass is not suitable for immobilization of nuclear waste from advanced reactors such as Fast Breeder Reactors (FBR) because solubility of many compounds/elements existing in the spent fuel in borosilicate glasses is quite poor. In order to possess a viable immobilization strategy for wastes arising from advanced reactors, alternatives to borosilicate glasses such as phosphate glasses, glassceramics and crystalline waste forms are being investigated. This review aims to provide an overview of nuclear waste immobilization employing phosphate-based glasses, glass-ceramics and crystalline ceramic hosts, focusing on structure and properties that make these new matrices suitable for the challenging task of waste immobilization.
Keywords:Nuclear waste,Vitrification;Glasses;Ceramics;Pyrochemical process
  1. Weber WJ, Navrotsky A, Stefanovsky S, Vance ER, Vernaz E, MRS Bull., 34(1), 46 (2009)
  2. Clavier N, Podor R, Dacheux N, J. European Ceram. Soc., 31(6), 941 (2011)
  3. Darab JG, Meiers EM, Smith PA, Behavior of Simulated Hanford Slurries During Conversion to Glass, MRS Proceedings, Cambridge Univ Press, 1999, pp. 215.
  4. Santana LP, Proc. Int. Acad. Ecol. Environ. Sci., 6(2), 38 (2016)
  5. Donald IW, Metcalfe BL, Taylor RN, J. Mater. Sci., 32(22), 5851 (1997)
  6. Mallampati SR, Mitoma Y, Okuda T, Simion C, Lee BK, J. Environ. Radioact., 139, 118 (2015)
  7. Huang W, Day DE, Ray CS, Kim CW, J. Nucl. Mater., 327(1), 46 (2004)
  8. Kim TY, An SS, Shim WG, Lee JW, Cho SY, Kim JH, J. Ind. Eng. Chem., 27, 260 (2015)
  9. Hatch L, Am. Sci., 41(3), 410 (1953)
  10. Ringwood A, Kesson S, Ware N, Hibberson W, A. Major, Nature, 278, 219 (1979)
  11. Zhang K, Yin D, Peng L, Zhang H, Ceram. Int., 42(9), 11387 (2016)
  12. Meng C, Ding XG, Li WQ, Zhao JC, Yang H, J. Mater. Sci., 51(11), 5207 (2016)
  13. Kwona SW, Ahn DH, Kim EH, Ahn HG, J. Ind. Eng. Chem., 15(1), 86 (2009)
  14. Yudintsev S, Stefanovsky S, Nikol’skii M, Stefanovskaya O, Nikonov B, Radiochemistry, 58(4), 333 (2016)
  15. Donald IW, Waste Immobilization in Glass and Ceramic Based Hosts: Radioactive, Toxic and Hazardous Wastes, John Wiley & Sons, 2010.
  16. Liu C, Heo J, J. Am. Ceram. Soc., 95(7), 2100 (2012)
  17. Caurant D, Loiseau P, Majerus O, Aubin-Chevaldonnet V, Bardez I, Quintas A, Glasses, Glass-ceramics and Ceramics for Immobilization of Highly Radioactive Nuclear Wastes, Nova Science Publishers, New York, 2009.
  18. McCarthy GJ, White WB, Pfoertsch DE, Mater. Res. Bull., 13(11), 1239 (1978)
  19. Clarke D, Annu. Rev. Mater. Sci., 13(1), 191 (1983)
  20. Meng C, Ding X, Zhao J, Ren C, Fu H, Yang H, J. European Ceram. Soc., 36(3), 773 (2016)
  21. Oelkers EH, Montel JM, Elements, 4(2), 113 (2008)
  22. Ewing RC, Wang L, Rev. Mineral. Geochem., 48(1), 673 (2002)
  23. Brow RK, J. Non-Cryst. Solids, 263, 1 (2000)
  24. Jadhav HS, Kalubarme RS, Jang SY, Jung KN, Shin KH, Park CJ, Dalton Trans., 43(30), 2014 (1172)
  25. Christie JK, Ainsworth RI, Tommaso DD, de Leeuw NH, J. Phys. Chem. B, 117(36), 11723 (2014)
  26. Goel NK, Pickrell G, Stolen R, An optical amplifier having 5 cm long silicaclad erbium doped phosphate glass fiber fabricated by core-suction technique, Opt. Fiber Technol. 20 (4) (2014) 325.
  27. Park HS, Cho IH, Eun HC, Kim IT, Cho YZ, Lee HS, Environ. Sci. Technol., 45(5), 1932 (2011)
  28. Kirkpatrick RJ, Brow RK, Solid State Nucl. Magn. Reson., 5(1), 9 (1995)
  29. Tiwari B, Pandey M, Sudarsan V, Deb S, Kothiyal G, Physica B, 404(1), 47 (2009)
  30. Fletcher LB, Witcher JJ, Troy N, Reis ST, Brow RK, Vazquez RM, Osellame R, Krol DM, Opt. Mater., 1(5), 845 (2011)
  31. Smith CE, Brow RK, Montagne L, Revel B, J. Non-Cryst. Solids, 386, 105 (2014)
  32. Hee P, Christensen R, Ledemi Y, Wren JE, Dussauze M, Cardinal T, Fargin E, Kroeker S, Messaddeq Y, J. Mater. Chem. C, 2(37), 7906 (2014)
  33. Schofield JM, Bingham PA, Hand RJ, MRS Proceedings, Cambridge Univ. Press, 2008, pp. 253.
  34. Day D, Wu Z, Ray C, Hrma P, J. Non-Cryst. Solids, 241(1), 1 (1998)
  35. Bingham P, Hand R, Hannant O, Forder S, Kilcoyne SH, J. Non-Cryst. Solids, 355(28), 1526 (2009)
  36. Lu Z, Hao Z, Wang J, Chen L, J. Ind. Eng. Chem., 34, 374 (2016)
  37. Day DE, Ray CS, A Review of Iron Phosphate Glasses and Recommendations for Vitrifying Hanford Waste, Idaho National Laboratory (INL), 2013.
  38. Mesko MG, Day D, J. Nucl. Mater., 273(1), 27 (1999)
  39. Day DE, Ray CS, Kim CW, Iron Phosphate Glasses: An Alternative for Vitrifying Certain Nuclear Wastes, University of Missouri-Rolla, US, 2004.
  40. Kim CW, Day DE, J. Non-Cryst. Solids, 331(1), 20 (2003)
  41. Yu X, Day DE, Long GJ, Brow RK, J. Non-Cryst. Solids, 215(1), 21 (1997)
  42. Hsu JH, Newkirk JW, Kim CW, Ray CS, Brow RK, Schlesinger ME, Day DE, Corrosion Sci., 75, 148 (2013)
  43. Yunfei L, Yan Z, Weiwei H, Kunquan L, Yaqin Z, J. Non-Cryst. Solids, 112(1-3), 136 (1989)
  44. Stoch P, Stoch A, Nukleonika, 60(1), 133 (2015)
  45. Joseph K, Jolley K, Smith R, J. Non-Cryst. Solids, 411, 137 (2015)
  46. Stoch P, Szczerba W, Bodnar W, Ciecinska M, Stoch A, Burkel E, PCCP, 16(37), 19917 (2014)
  47. Geel JV, Eschrich H, Heimerl W, Grziwa P, IAEA (1976) 22.
  48. Bingham P, Connelly A, Hyatt N, Hand R, Int. Mater. Rev., 56(4), 226 (2011)
  49. Sengupta P, Kaushik CP, Mishra RK, Kale GB, J. Am. Ceram. Soc., 90(10), 3057 (2007)
  50. Gan H, Buechele A, Kim CW, Huang X, Mohr R, Pegg I, Corrosion of Inconel-690 Electrodes in Waste Glass Melts, MRS Proceedings, Cambridge Univ. Press, 1999, pp. 287.
  51. Vidensky I, Gan H, Pegg IL, Corrosion of Ni.Cr alloys in molten salts and Hanford law waste glass, Environmental Issues and Waste Management Technologies in the Ceramic and Nuclear Industries VII, The American Ceramic Society, Ceramic Place Westerville, Ohio, 2002, pp. 141.150.
  52. Hsu JH, Newkirk JW, Kim CW, Brow RK, Schlesinger ME, Ray CS, Day DE, J. Nucl. Mater., 444(1), 323 (2014)
  53. Bingham PA, Hand RJ, Forder SD, Mater. Res. Bull., 41(9), 1622 (2006)
  54. Donald IW, Metcalfe B, J. Non-Cryst. Solids, 348, 118 (2004)
  55. Mogus-Milankovic A, Pavic L, Ertap H, Karabulut M, J. Am. Ceram. Soc., 95(6), 2007 (2012)
  56. Karabulut M, Yuce B, Bozdogan O, Ertap H, Mammadov G, J. Non-Cryst. Solids, 357(5), 1455 (2011)
  57. Lu M, Wang F, Chen K, Dai Y, Liao Q, Zhu H, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 148, 1 (2015)
  58. Russo DO, Rodriguez DS, Romero M, Oliver CJG, J. Non-Cryst. Solids, 354(14), 1541 (2008)
  59. Kiran N, J. Mol. Struct., 1065, 93 (2014)
  60. Xu K, Hrma P, Um W, Heo J, J. Nucl. Mater., 441(1), 262 (2013)
  61. Yan Y, Faber AJ, Waal H, J. Am. Ceram. Soc., 79(1), 286 (1996)
  62. Egan J, Wenslow R, Mueller K, J. Non-Cryst. Solids, 261(1), 115 (2000)
  63. Aloy A, Bel‘yukov V, Demin A, Revenko Y, Experiences with Vitrification of HLW and Development of New Approaches in Russia. Glass as a Waste Form and Vitrification Technology: Summary of an International Workshop, National Academy Press, Washington, 1996 p. E. 50.
  64. Donald IW, Metcalfe B, Greedharee R, Thermal stability and crystallization of iron phosphate based glasses, Int. Symposium on Crystallization in Glasses and Liquids (2000) 74.
  65. Donald IW, Metcalfe B, Fong S, Gerrard L, J. Non-Cryst. Solids, 352(28), 2993 (2006)
  66. Stefanovsky S, Myasoedov B, Remizov M, Belanova E, J. Appl. Spectrosc., 81(4), 618 (2014)
  67. Tran TD, Sidebottom DL, J. Am. Ceram. Soc., 96(7), 2147 (2013)
  68. Brow RK, Kirkpatrick RJ, Turner GL, J. Am. Ceram. Soc., 76(4), 919 (1993)
  69. Wullen L, Van S, Wegner G, Tricot J, J. Phys. Chem. B, 111(26), 7529 (2007)
  70. Stefanovsky SV, Shiryaev AA, Remizov MB, Belanova EA, Kozlov PA, Myasoedov BF, MRS Proceedings, Cambridge Univ. Press, 2015, pp. 73.
  71. Remizov M, Belanova E, Stefanovsky S, Myasoedov B, Nikonov B, Glass Phys. Chem., 40(5), 534 (2014)
  72. Nishida T, Maki K, Radioanal J, Nucl. Chem., 242(2), 557 (1999)
  73. Sun K, Wang L, Ewing RC, Weber WJ, Philos. Mag. B-Phys. Condens. Matter Stat. Mech. Electron. Opt. Magn. Prop., 85(4-7), 597 (2005)
  74. Zotov A, Levin K, Magazina L, Mukhamet-Galeev A, Omel'yanenko B, Samotoin N, Shapovalov YB, Geokhimiya, 9, 891 (1996)
  75. Mizusaki S, Toyoda Y, Nakayama K, Nagata Y, Ozawa T, Noro Y, Samata H, Catalysis, J. Non-Cryst. Solids, 355(16), 960 (2009)
  76. Unruh T, Schulte A, Guo Y, Schirmacher W, Schmid B, J. Non-Cryst. Solids, 357(2), 506 (2011)
  77. Sene F, Martinelli J, Gomes L, J. Non-Cryst. Solids, 348, 63 (2004)
  78. Sirleto L, Donato M, Messina G, Santangelo S, Lipovskii A, Tagantsev D, Pelli S, Righini G, Appl. Phys. Lett., 94(3), 031105 (2009)
  79. Ghussn L, Prado M, Russo D, Martinelli J, J. Non-Cryst. Solids, 352(32), 3391 (2006)
  80. El Jazouli A, Viala J, Parent C, Le Flem G, Hagenmuller P, J. Solid State Chem., 73(2), 433 (1988)
  81. Cardinal T, Fargin E, Le Flem G, Couzi M, Canioni L, Segonds P, Ducasse A, Adamietz F, Eur. J. Solid State Inorg. Chem., 33, 597 (1996)
  82. Cardinal T, Fargin E, Le Flem G, Leboiteux S, J. Non-Cryst. Solids, 222, 228 (1997)
  83. Koudelka L, Kalenda P, Mosner P, Montagne L, Revel B, J. Non-Cryst. Solids, 437, 64 (2016)
  84. Chu CM, Wu JJ, Yung SW, Chin TS, Zhang T, Wu FB, J. Non-Cryst. Solids, 357(3), 939 (2011)
  85. Melo BMG, Graca MPF, Prezas PR, Valente MA, Almeida AF, Freire FNA, Bih L, J. Non-Cryst. Solids, 434, 28 (2016)
  86. Ghussn L, Martinelli J, Russo D, IAEA, 41(9), 1 (2009)
  87. Ghussn L, Martinelli J, Russo D, J. Glass Sci. Technol. A, 50(5), 269 (2009)
  88. Carvalho C, Martinelli J, Bauer J, Haapasalo M, Shen Y, Bradaschia-Correa V, Manso A, Gavini G, Int. Endod. J., 48(5), 451 (2015)
  89. Abd El-Ati MI, Higazy AA, J. Mater. Sci., 35(24), 6175 (2000)
  90. Rambo C, Ghussn L, Sene F, Martinelli J, J. Non-Cryst. Solids, 352(32), 3739 (2006)
  91. Vieira H, IAEA, 39(43), 1 (2008)
  92. Choi JH, Eun HC, Lee KR, Cho IH, Lee TK, Park HS, Ahn DS, J. Non-Cryst. Solids, 434, 79 (2016)
  93. Audubert F, Carpena J, Lacout JL, Tetard F, Solid State Ion., 95(1-2), 113 (1997)
  94. Clark WE, Thompson CT, Immobilization of iodine in concrete (1977), US patent 4017417.
  95. Lemesle T, Mear FO, Campayo L, Pinet O, Revel B, Montagne L, J. Hazard. Mater., 264, 117 (2014)
  96. Konidakis C, Varsamis E, Kamitsos J, J. Non-Cryst. Solids, 357(14), 2684 (2011)
  97. Novita DI, Boolchand P, Phys. Rev. B, 76(18), 184205 (2007)
  98. Maji BK, Jena H, Krishnaiah M, Asuvathraman R, J. Therm. Anal. Calorim., 124(2), 857 (2016)
  99. Lewis MA, Fischer DF, Smith LJ, J. Am. Ceram. Soc., 76(11), 2826 (1993)
  100. Ojovan MI, Lee WE, An Introduction to Nuclear Waste Immobilisation, Elsevier, Oxford, 2005.
  101. Kim HY, Kim JG, Kim IT, Park HS, J. Ind. Eng. Chem., 15(3), 293 (2009)
  102. Metcalfe B, Donald I, J. Non-Cryst. Solids, 348, 225 (2004)
  103. Park HS, Kim IT, Cho YZ, Eun HC, Lee HS, Environ. Sci. Technol., 42(24), 9357 (2008)
  104. McCarthy GJ, Nucl. Technol., 32(1), 92 (1977)
  105. Lobaina T, Zhurbenko R, Alfonso I, Rodriguez C, Gala-Garcia A, Gontijo SL, Cortes ME, Gomes A, Sinisterra RD, Biointerphases, 9(2), 029018 (2014)
  106. Wagh AS, Drozd V, Inorganic phosphate corrosion resistant coatings (2013), US Patent US8557342.
  107. Kaygili O, Keser S, Ates T, Yakuphanoglu F, Ceram. Int., 39(7), 7779 (2013)
  108. Wagh AS, ISRN Ceram. 2013 (2013).
  109. Singh D, Mandalika V, Parulekar S, Wagh A, J. Nucl. Mater., 348(3), 272 (2006)
  110. Catlos EJ, Am. Mineral., 98(5-6), 819 (2013)
  111. Ewing R, Weber W, Clinard F, Prog. Nucl. Energy, 29(2), 63 (1995)
  112. Dacheux N, Clavier N, Podor R, Am. Mineral., 98, 833 (2013)
  113. Boatner LA, Rev. Mineral. Geochem., 48(1), 87 (2002)
  114. Burakov BE, Yagovkina MA, Garbuzov VM, Kitsay AA, Zirlin VA, Selfirradiation of Monazite Ceramics: Contrasting Behavior of PuPO4 and (La,Pu) PO4 Doped With Pu-238, MRS Proceedings, Cambridge Univ. Press, 2004 p. CC4.1.
  115. Gallini S, Jurado J, Colomer M, Chem. Mater., 17(16), 4154 (2005)
  116. Lucas S, Champion E, Penot C, Leroy G, Bernache-Assollant D, Synthesis and Characterization of Rare Earth Phosphate Powders, Key Eng. Mater., Trans Tech Publ., 2001, pp. 47.
  117. Mian-Zeng S, Ji Z, Kui-Su S, J. Alloy. Compd., 207-208, 406 (1994)
  118. Heuser J, Bukaemskiy A, Neumeier S, Neumann A, Bosbach D, Prog. Nucl. Energy, 72, 149 (2014)
  119. Hukuo K, Hikichi Y, Bull. Nagoya Inst. Technol., 31, 175 (1979)
  120. Berbon M, Davis J, Marshall D, Housley R, Morgan P, Int. J. Mater. Res., 98(12), 1244 (2007)
  121. Chen P, Mah TI, J. Mater. Sci., 32(14), 3863 (1997)
  122. Schatzmann MT, Mecartney ML, Morgan PE, J. Mater. Chem., 19(32), 5720 (2009)
  123. Asuvathraman R, Kutty KVG, Thermochim. Acta, 581, 54 (2014)
  124. Li W, Lee J, J. Phys. Chem. C, 112(31), 11679 (2008)
  125. del Moral EG, Fagg DP, Chinarro E, Abrantes JC, Jurado JR, Mather GC, Ceram. Int., 35(4), 1481 (2009)
  126. Colomer MT, Diaz-Guillen JA, Fuentes AF, J. Am. Ceram. Soc., 93(2), 393 (2010)
  127. Vance E, Carter M, Begg B, Day R, Leung S, Solid Solubilities of Pu, U, Hf and Gd in Candidate Ceramic Phases for Actinide Waste Immobilization, MRS Proceedings, Cambridge Univ Press, 1999 p. 431.
  128. Montel JM, Glorieux B, Seydoux-Guillaume AM, Wirth R, J. Phys. Chem. Solids, 67(12), 2489 (2006)
  129. Zeng P, Teng Y, Huang Y, Wu L, Wang X, J. Nucl. Mater., 452(1), 407 (2014)
  130. Yang H, Teng Y, Ren X, Wu L, Liu H, Wang S, Xu L, J. Nucl. Mater., 444(1), 39 (2014)
  131. Kumar SP, Gopal B, J. Am. Ceram. Soc., 94(4), 1008 (2011)
  132. Kumar SP, Gopal B, J. Nucl. Mater., 485, 224 (2015)
  133. Terra O, Clavier N, Dacheux N, Podor R, New J. Chem., 27(6), 957 (2003)
  134. Brandt F, Neumeier S, Schuppik T, Arinicheva Y, Bukaemskiy A, Modolo G, Bosbach D, Prog. Nucl. Energy, 72, 140 (2014)
  135. Yudintsev S, Stefanovsky S, Ewing R, Actinide host phases as radioactive waste forms, Structural Chemistry of Inorganic Actinide Compounds, Elsevier Science B.V., Amsterdam, 2007, pp. 453.
  136. Gross K, J. Aust. Ceram. Soc., 50(1), 74 (2014)
  137. Audubert F, Carpena J, Lacout J, Tetard F, Solid State Ionics, 95(1), 113 (1997)
  138. Horie K, Hidaka H, Gauthier-Lafaye F, Geochim. Cosmochim. Acta, 68(1), 115 (2004)
  139. Arakcheeva A, Chapuis G, Petricek V, Dusek M, Schoenleber A, Acta Crystallogr. Sect. B-Struct. Sci., 59(1), 17 (2003)
  140. Jay EE, Fossati PC, Rushton MJ, Grimes RW, J. Mater. Chem., 3(3), 1164 (2015)
  141. Vance ER, Ball CJ, Begg BD, Carter ML, Day RA, Thorogood GJ, J. Am. Ceram. Soc., 86(7), 1223 (2003)
  142. Fong S, Donald I, Metcalfe B, J. Alloy. Compd., 444, 424 (2007)
  143. Metcalfe BL, Donald IW, Fong SK, Gerrard LA, Strachan DM, Scheele RD, J. Nucl. Mater., 385(2), 485 (2009)
  144. Jackson M, Jay E, Rushton M, Grimes RA, J. Mater. Chem., 2(38), 16157 (2014)
  145. Coulon A, Laurencin D, Grandjean A, Coumes CCD, Rossignol S, Campayo L, J. Mater. Chem., A2, 20923 (2014)
  146. Pet'kov V, Asabina E, Loshkarev V, Sukhanov M, J. Nucl. Mater., 471, 122 (2016)
  147. Alamo J, Solid State Ionics, 63, 547 (1993)
  148. Pet'kov VI, Russ. Chem. Rev., 81(7), 606 (2012)
  149. Sukhanov M, Pet’kov V, Firsov D, Inorg. Mater., 47(6), 674 (2011)
  150. Kelleher ME, Kilcoyne I, Dechant JE, Hummer E, Kass PH, Snyder JRA, Vet. Surg., 44(3), 359 (2015)
  151. Scheetz B, Agrawal D, Breval E, Roy R, Waste Manage., 14(6), 489 (1994)
  152. Roy R, Vance E, J. Alamo, Mater. Res. Bull., 17(5), 585 (1982)
  153. Pet'kov VI, Sukhanov MV, Kurazhkovskaya VS, Radiochemistry, 45(6), 620 (2003)
  154. Hagman LO, Kierkegaard P, Acta Chem. Scand., 22(6), 1822 (1968)
  155. Shrivastava O, Chourasia R, J. Hazard. Mater., 153(1), 285 (2008)
  156. Chourasia R, Shrivastava O, Ambashta R, Wattal P, Ann. Nucl. Energy, 37(2), 103 (2010)
  157. Chourasia R, Bohre A, Ambastha RD, Shrivastava OP, Wattal PK, J. Mater. Sci., 45(2), 533 (2009)
  158. Shrivastava OP, Chourasia R, Kumar N, Ann. Nucl. Energy, 35(6), 1147 (2008)
  159. Shrivastava OP, Chourasia R, J. Chem. Crystallogr., 38(5), 357 (2007)
  160. Kumar SP, Guvaneswari G, Madhavan RR, Govindan Kutty KV, Radiochemistry, 53(4), 421 (2011)
  161. Bohre A, Shrivastava OP, J. Nucl. Mater., 433(1-3), 486 (2013)
  162. Bohre A, Shrivastava OP, Int. J. Appl. Ceram. Technol., 10(3), 552 (2013)
  163. Nakayama S, Itoh K, J. Nucl. Sci. Technol., 40(8), 631 (2003)
  164. Agrawal DK, Harshe G, Breval E, Roy R, J. Mater. Res., 11(12), 3158 (1996)
  165. Kamali K, Ravindran T, Shekar NC, Pandey K, Sharma S, J. Solid State Chem., 221, 285 (2015)
  166. Pet'kov V, Orlova A, Kazantsev G, Samoilov S, Spiridonova M, J. Therm. Anal. Calorim., 66(2), 623 (2001)
  167. Orlova A, Radiochemistry, 44(5), 423 (2002)
  168. Angadi B, Jali V, Lagare M, Kini N, Umarji A, Kumar R, Arora S, Kanjilal D, Phys. Rev. B, 187(1), 87 (2002)
  169. Orlova A, Volgutov VV, Mikhailov D, Bykov D, Skuratov V, Chuvil’deev V, Nokhrin A, Boldin M, Sakharov N, J. Nucl. Mater., 446(1), 232 (2014)
  170. Gregg DJ, Karatchevtseva I, Thorogood GJ, Davis J, Bell BD, Jackson M, Dayal P, Ionescu M, Triani G, Short K, J. Nucl. Mater., 446(1), 224 (2014)
  171. Sugantha M, Kumar N, Varadaraju U, Waste Manage., 18(4), 275 (1998)
  172. Buvaneswari G, Varadaraju U, Mater. Res. Bull., 35(8), 131 (2000)
  173. Pet’kov V, Asabina E, Lukuttsov A, Korchemkin I, Alekseev A, Demarin V, Radiochemistry, 57(6), 632 (2015)
  174. Dey A, Gupta AD, Basu D, Ambashta RD, Wattal P, Kumar S, Body M, Rajamohanan P, J. Radioanal. Nucl. Chem., 299(1), 19 (2014)
  175. Dey A, Gupta AD, Basu D, Ambashta RD, Wattal PK, Kumar S, Sen D, Mazumder S, Ceram. Int., 39(8), 9351 (2013)
  176. Naik A, Deb S, Chalke A, Saxena M, Ramakumar K, Venugopal V, Dharwadkar S, J. Chem. Sci., 122(1), 71 (2010)
  177. Pet'kov V, Loshkarev V, Orlova A, Kurazhkovskaya V, Demarin V, Russ. J. Appl. Chem., 47(7), 1053 (2002)
  178. Bohre A, Shrivastava O, Avasthi K, Arabian J. Chem., 9(5), 736 (2016)
  179. Dacheux N, Podor R, Chassigneux B, Brandel V, Genet M, J. Alloy. Compd., 271, 236 (1998)
  180. Dacheux N, Grandjean S, Rousselle J, Clavier N, Inorg. Chem., 46(24), 10390 (2007)
  181. Brandel V, Dacheux N, Genet M, Radiochemistry, 43(1), 16 (2001)
  182. Benard P, Brandel V, Dacheux N, Jaulmes S, Launay S, LindeckerC, Genet M, Louer D, Quarton M, Chem. Mater., 8(1), 181 (1996)
  183. Dacheux N, Podor R, Brandel V, Genet M, J. Nucl. Mater., 252(3), 179 (1998)
  184. Tamain C, Garrido F, Thome L, Dacheux N, Ozgumus A, J. Nucl. Mater., 373(1), 378 (2008)
  185. Dacheux N, Clavier N, Ritt J, J. Nucl. Mater., 349(3), 291 (2006)
  186. Clavier N, De Kerdaniel EDF, Dacheux N, Le Coustumer P, Drot R, Ravaux J, Simoni E, J. Nucl. Mater., 349(3), 304 (2006)
  187. Robisson A, Dacheux N, Aupiais J, J. Nucl. Mater., 306(2), 134 (2002)
  188. Pet'kov V, Korchemkin I, Asabina E, Zaripov A, Chuvii'deev V, Kurazhkovskaya V, Borovikova EY, Ceram. Trans., 233, 83 (2012)
  189. Aloy AS, Kovarskaya EN, Koltsova TI, Macheret Y, Medvedev PG, Todd T, Iron-phosphate ceramics for solidification of mixed low-level waste (2000). US Patent: US 6075176.
  190. Choi J, Um W, Choung S, J. Nucl. Mater., 452(1), 16 (2014)
  191. Yang JH, Shin JM, Lee CH, Heo CM, Jeon MK, Kang KH, Radioanal J, Nucl. Chem., 295(1), 211 (2013)
  192. Bozadzhiev L, Georgiev G, Bozadzhiev R, Sci. Sinter., 43(2), 225 (2011)
  193. Rawlings RD, Wu JP, Boccaccini AR, J. Mater. Sci., 41(3), 733 (2006)
  194. Loiseau P, Caurant D, Baffier N, Mazerolles L, Fillet C, J. Nucl. Mater., 335(1), 14 (2004)
  195. Kapoor S, Goe A, Pascual MJ, Ferreira JM, J. Non-Cryst. Solids, 432, 81 (2016)
  196. Wang F, Liao Q, Zhu H, Dai Y, Wang H, J. Mol. Struct., 1109, 226 (2016)
  197. Vlasov V, Kedrovskij O, Nikiforov A, Polyakov A, Shishchits IY, Handling of liquid radioactive waste from the closed nuclear fuel cycle, Back End of the Nuclear Fuel Cycle: Strategies and Options, International Atomic Energy Agency, Vienna, 1987.
  198. Al-Sanabani JS, Madfa AA, Al-Sanabani FA, Int. J. Biomater. P12 (2013) Article ID 876132.
  199. Jha PK, Pandey O, Singh K, J. Mol. Struct., 1083, 278 (2015)
  200. Wang K, Russel C, Liu CS, Mater. Chem. Phys., 111(1), 106 (2008)
  201. Karabulut M, Aydın C, Ertap H, Yuksek M, J. Non-Cryst. Solids, 411, 19 (2015)
  202. Kim M, Heo J, Ceram. Int., 41(4), 6132 (2015)
  203. He Y, Lu Y, Zhang Q, J. Nucl. Mater., 376(2), 201 (2008)
  204. Vance E, Day R, Carter M, Jostsons A, A Melting Route to Synroc for Hanford HLW Immobilization, MRS Proceedings, Cambridge Univ. Press, 1995 p. 289.