화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.50, 133-141, June, 2017
DOI10.1016/j.jiec.2017.02.006  Export Citation
Removal characteristics of nitrogen oxides and particulates of a novel Mn-Ce-Nb-Ox/P84 catalytic filter applied for cement kiln
Bo Yang1, 2, Yuesong Shen1, 2, Yun Su2, Peiwen Li3, Yanwei Zeng1, Shubao Shen4, and Shemin Zhu1, 2, †
  • 1College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009, PR China
  • 2Jiangsu Collaborative Innovation Center for Advanced Inorganic Function Composites, Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing Tech University, Nanjing, Jiangsu, 210009, PR China
  • 3Department of Aerospace and Mechanical Engineering, The University of Arizona, Tucson, AZ, 85721-0119, USA
  • 4Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, Nanjing 210009, PR China
E-mail:
A novel Mn-Ce-Nb-Ox/P84 catalytic filter for synergetic removal of particulates and NO was designed and prepared by a new method using functional foaming coating. Removal characteristics of nitrogen oxides (including catalyst loading amount, O2 concentration, NH3/NO molar ratio, H2O and SO2) and particulates, were systematically studied. Results showed that the NO removal efficiency of catalytic filter reached 95.3% at 200 C, as the catalyst loading amount, filtration velocity and mole ratio of NH3/NO were set to be 450 g/m2, 1 m/min and 1, respectively. The removal characteristic of particulates of Mn-Ce-Nb-Ox/P84 catalytic filter belonged surface filtration and the PM2.5 removal efficiency reached 99.98%.
Keywords:Synergetic removal;NO;particulates;Mn-Ce-Nb-Ox/P84 catalytic;filters;PTFE-based foaming coating
  1. Khalil NM, Hassan EM, Shakdofa MME, Farahat M, J. Ind. Eng. Chem., 20(5), 2998 (2014)
  2. Hua SB, Tiana HZ, Wang K, Zhu CY, Gao JJ, Ma YL, Xue YF, Wang Y, Duan SH, Zhou JR, Atmos. Environ., 128, 1 (2016)
  3. Chen H, Chen DZ, Fan S, Hong L, Wang D, Chemosphere, 161, 208 (2016)
  4. Zhang XH, Zhou J, Sun SZ, Sun R, Qin M, Fuel, 142, 215 (2015)
  5. Saracco G, Specchia S, Specchia V, Chem. Eng. Sci., 51(24), 5289 (1996)
  6. Nacken M, Heidenreich S, Hackel M, Schaub G, Appl. Catal., 70, 370 (2007)
  7. Heidenreich S, Nacken M, Hackel M, Schaub G, Powder Technol., 180(1-2), 86 (2008)
  8. Fino D, Russo N, Saracco G, Specchia V, Chem. Eng. Sci., 59(22-23), 5329 (2004)
  9. Kang YS, Kim SS, Hong SC, J. Ind. Eng. Chem., 30, 197 (2015)
  10. Yang B, Shen YS, Zeng YW, Li B, Shen SB, Zhu SM, J. Mol. Catal. A-Chem., 418, 138 (2016)
  11. Yang B, Shen Y, Zeng Y, Shen S, Zhu S, Nanjing J, Tech. Univ., 37, 6 (2015)
  12. Galka N, Saxena A, Filtr. Sep., 46(4), 22 (2009)
  13. Pedram MZ, Omidkhah M, Amooghin AE, J. Ind. Eng. Chem., 20(1), 74 (2014)
  14. Lupion M, Ortiz FJG, Navarrete B, Cortes VJ, Fuel, 89(4), 848 (2010)
  15. Lu PW, The Scientific Basics of Inorgnic Materials, 2nd ed., (2003).
  16. Lian ZH, Liu FD, He H, Shi XY, Mo JS, Wu ZB, Chem. Eng. J., 250, 390 (2014)
  17. Du X, Wang X, Chen Y, Gao X, Zhang L, J. Ind. Eng. Chem., 36, 271 (2016)
  18. Wu ZB, Jin RB, Wang HQ, Liu Y, Catal. Commun., 10, 935 (2009)
  19. Zhang QM, Song CL, Lv G, Bin F, Pang HT, Song JO, J. Ind. Eng. Chem., 24, 79 (2015)
  20. Kang M, Park ED, Kim JM, Yie JE, Appl. Catal., 327, 261 (2007)
  21. Li YR, Guo YY, Xiong J, Zhu TY, Hao JK, Ind. Eng. Chem. Res., 55(48), 12341 (2016)
  22. Li P, Xin Y, Li Q, Wang ZP, Zhang ZL, Zheng L, Environ. Sci. Technol., 46, 9600 (2012)
  23. Ding S, Liu FD, Shi XY, Liu K, Lian ZH, Xie LJ, He H, ACS Appl. Mater Interfaces, 7, 9497 (2015)
  24. Gunter T, Pesek J, Schafer K, Abai AB, Casapu M, Deutschmann O, Grunwaldt JD, Appl. Catal. B: Environ., 198, 548 (2016)
  25. Wang LK, Pereira NC, Hung, Hung Y, Air Pollution Control Engineering, Humana Press, 2004.
  26. Niu Yanqing, Shang Tong, Hui Shien, Zhang Xiaolu, Lei Yu, Lv Yuan, Wang Shui, Fuel, 185, 316 (2016)
  27. Jing GH, Li JH, Yang D, Hao JM, Appl. Catal. B: Environ., 91(1-2), 123 (2009)
  28. Lietti L, Forzatti P, J. Catal., 147(1), 241 (1994)
  29. Liu LJ, Liu B, Dong LH, Zhu J, Wan HQ, Sun KQ, Zhao B, Zhu HY, Dong L, Chen Y, Appl. Catal. B: Environ., 90(3-4), 578 (2009)
  30. Xie GY, Liu ZY, Zhu ZP, Liu QY, Ge J, Huang ZG, J. Catal., 224(1), 36 (2004)
  31. Li Y, Li YQ, Wan Y, Zhan SH, Guan QX, Tian Y, RSC Adv., 6, 54926 (2016)
  32. Zhou H, Su YX, Liao WY, Deng WY, Zhong FC, Fuel, 182, 352 (2016)
  33. Kwon DW, Nam KB, Hong SC, Appl. Catal., 166-167, 37 (2015)
  34. Jangjou Y, Wang D, Kumar A, Li JH, Epling WS, ACS Catal., 6, 6612 (2016)
  35. Wang Haiming, Xie Dong, Chen Qun, You Changfu, Chem. Eng. J., 303, 425 (2016)
  36. Huang ZG, Liu ZY, Zhang XL, Liu QY, Appl. Catal. B: Environ., 63(3-4), 260 (2006)
  37. Tanabe K, Catal. Today, 78(1-4), 65 (2003)
  38. Casapu M, Krocher O, Elsener M, Appl. Catal. B: Environ., 88(3-4), 413 (2009)
  39. Hata M, Furuuchi M, Kanaoka C, Kurose R, Makino H, Adv. Powder Technol., 14(6), 719 (2003)
  40. Park BH, Kim SB, Lee MH, Kim KS, Jo YM, J. Air Waste Manage. Assoc., 60, 137 (2010)
  41. Simon X, Chazelet S, Thomas D, Bemer D, Regnier R, Powder Technol., 172(2), 67 (2007)