Salt effect on the liquid-liquid equilibrium of water-furfuryl alcohol-furfural system at 298.15 K

Naphaphan Kunthakudee; Ura Pancharoen; Katarína Fulajtárová; Tomáš Soták; Milan Hronec; Prakorn Ramakul

Korean Journal of Chemical Engineering, Vol.34, No.8, 2293-2300, August, 2017

DOI10.1007/s11814-017-0136-8 Export Citation

Salt effect on the liquid-liquid equilibrium of water-furfuryl alcohol-furfural system at 298.15 K

Naphaphan Kunthakudee, Ura Pancharoen¹, Katarína Fulajtárová², Tomáš Soták², Milan Hronec², and Prakorn Ramakul^†

Department of Chemical Engineering, Faculty of Engineering and Industrial Technology, Silpakorn University, Muang, Nakhon Pathom 73000, Thailand
¹Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Patumwan, Bangkok 10330, Thailand
²Department of Organic Technology, Slovak University of Technology, Radlinského 9, 812 37, Bratislava, Slovakia, Slovakia (Slovak Republic)

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Salt effect on the liquid phase equilibrium of the water-furfuryl alcohol-furfural system at 298.15 K was studied. The effects of salt concentration (1, 3 and 10% w/wNaCl) and type of salt (LiCl, KCl and RbCl) were investigated. The solubility and tie-line data of these systems were determined by experimental analysis. The results showed that addition of salt significantly affected the two-phase region of ternary system; the enlargement of two-phase region occurred with an increase of salt concentration in initial aqueous phase and the type of the salt in the following order: LiCl>NaCl>KCl>RbCl. Distribution coefficients and separation factors were also calculated. The reliability of the LLE experimental results was validated by the Othmer-Tobias equation, Hand equation and Bachman equation. NRTL was employed to correlate the results obtained by the modeling with the experimental data. Good correlation result was confirmed by the rmsd values of less than 0.3%.

Keywords:Salt Effect;Furfuryl Alcohol;Furfural;Liquid-liquid Equilibrium;Tie-line Data

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[2] Nagaraja BM, Padmasri AH, Raju BD, Rao KSR, J. Mol. Catal. A-Chem., 265(1-2), 90 (2007)

[3] O'Driscoll A, Leahy JJ, Curtin T, Catal. Today, 279, 194 (2017)

[4] Fulajtarova K, Sotak T, Hronec M, Vavra I, Dobrocka E, Omastova M, Appl. Catal. A: Gen., 502, 78 (2015)

[5] Vakili-Nezhaad GR, Mohsen-Nia M, Taghikhani V, Behpoor M, Aghahosseini M, J. Chem. Thermodyn., 36(4), 341 (2004)

[6] Choi MW, Chang YW, Appl. Chem., 4(1), 17 (2000)

[7] Euchi NB, Meniai AH, Gouaoura A, J. Polytechnic, 129, 20 (2017)

[8] Ghalami-Choobar B, Ghanadzadeh A, Kousarimehr S, Chin. J. Chem. Eng., 19(4), 565 (2011)

[9] Roy BC, Awual MR, Goto M, J. Appl. Sci., 7, 1053 (2007)

[10] Ghalami-Choobaret B, J. Mol. Liq., 222, 558 (2016)

[11] Wannachod T, Hronec M, Sotak T, Fulajtarova K, Pancharoen U, Nootong K, J. Chem. Eng. Data, 61(7), 2433 (2016)

[12] Wannachod T, Hronec M, Sotak M, Fulajtarova K, Pancharoen U, Arpornwichanop A, J. Mol. Liq., 218, 50 (2016)

[13] Shekarsaraee S, Phys. Chem. Res., 4, 507 (2016)

[14] Chawong K, Eng. Trans., 15, 6 (2012)

[15] Wang CX, Liu XJ, Fluid Phase Equilib., 392, 43 (2015)

[16] Hasseine A, Meniai AH, Korichi M, Desalination, 242(1-3), 264 (2009)

[17] Wongsawa T, Hronec M, Sotak T, Leepipatpiboon N, Pancharoen U, Phatanasri S, Fluid Phase Equilib., 365, 88 (2014)

[18] Othmer DF, Tobias PE, Ind. Eng. Chem., 34, 690 (1942)

[19] Hand DB, J. Phys. Chem., 34, 1961 (1929)

[20] Bachman I, Ind. Eng. Chem. Anal. Ed., 12, 38 (1940)

[21] Wongsawa T, Hronec M, Lothongkum AW, Pancharoen U, Phatanasri S, J. Mol. Liq., 196, 98 (2014)