New insights into surface-functionalized swelling high charged micas: Their adsorption performance for non-ionic organic pollutants

M. Carolina Pazos; Miguel A. Castro; Augustin Cota; Francisco J. Osuna; Esperanza Pavon; María D. Alba

Journal of Industrial and Engineering Chemistry, Vol.52, 179-186, August, 2017

DOI10.1016/j.jiec.2017.03.042 Export Citation

New insights into surface-functionalized swelling high charged micas: Their adsorption performance for non-ionic organic pollutants

M. Carolina Pazos, Miguel A. Castro¹, Augustin Cota², Francisco J. Osuna¹, Esperanza Pavon³, and María D. Alba^{1, †}

Escuela de Ciencias Químicas, Universidad Pedago’gica y Tecnolo’gica de Colombia, UPTC, Avda. Central del Norte, Via Paipa Tunja, 39-115 Boyaca’, Colombia
¹Instituto Ciencia de Materiales de Sevilla (CSIC-US), Avda. Américo Vespucio, 49.41092 Sevilla, Spain
²Laboratorio de Rayos-X, CITIUS, Avda. Reina Mercedes, 4.41012 Sevilla, Spain
³Center for the Development of Nanoscience and Nanotechnology, 9170124 Santiago, Chile

E-mail:

The major components of the wastewater from the petroleum refineries are benzene, toluene and phenol and one of the techniques applied to the treatment of effluents is sorption using organo functionalized clay. The materials exploited in the present study are a family of surface-functionalized synthetic micas and their sorption capacities for non-ionic organic pollutants are analyzed. The organo functionalization of their surface provides them the capacity to sorb effectively non-ionic pollutants in the interface. Their adsorption performance is a function of the alkylamonium properties such as the chain length, the mass fraction and the organization of the organic cation in the interlayer space of the micas.

Keywords:Organo-functionalization;Organic pollutants;Sorption isotherm;Interface adsorption

[References]

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Manjare SD, Ghoshal AK, Ind. Eng. Chem. Res., 45(19), 6563 (2006)
Yu SJ, Wang XX, Ai YJ, Tan XL, Hayat T, Hu WP, Wang XK, J. Mater. Chem., 4, 5654 (2016)
Jin ZX, Wang XX, Sun YB, Ai YJ, Wang XK, Environ. Sci. Technol., 49, 9168 (2015)
Zaitan H, Bianchi D, Achak O, Chafik T, J. Hazard. Mater., 153(1-2), 852 (2008)
Hu Q, Li JJ, Hao ZP, Li LD, Qiao SZ, Chem. Eng. J., 149(1-3), 281 (2009)
Zou YD, Wang XX, Chen ZS, Yao W, Ai YJ, Liu TH, Hayat T, Alsaedi A, Alharbi NS, Wang XK, Environ. Pollut., 219, 107 (2016)
Ko CH, Fan C, Chiang PN, Wang MK, Lin KC, J. Hazard. Mater., 149(2), 275 (2007)
Richards S, Bouazza A, Appl. Clay Sci., 37, 133 (2007)
Mangrulkar PA, Kamble SP, Meshram J, Rayalu SS, J. Hazard. Mater., 160(2-3), 414 (2008)
Nunes CD, Pires J, Carvalho AP, Calhorda MJ, Ferreira P, Microporous Mesoporous Mater., 111, 612 (2008)
Khenifi A, Zohra B, Kahina B, Houari H, Zoubir D, Chem. Eng. J., 146(3), 345 (2009)
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Klapyta Z, Fujita T, Iyi N, Appl. Clay Sci., 19, 5 (2001)
Klapyta Z, Gawel A, Fujita T, Iyi N, Clay Miner, 38, 151 (2003)
Alba MA, Castro MA, Naranjo M, Pavon E, Chem. Mater., 18, 2867 (2006)
Esfandiari A, Nazokdast H, Rashidi AS, Yazdanshenas ME, J. Appl. Sci., 8, 545 (2008)
Alba MD, Castro MA, Orta MM, Pavon E, Pazos MC, Rios JSV, Langmuir, 27(16), 9711 (2011)
Pazos MC, Castro MA, Orta MM, Pavon E, Rios JSV, Alba MD, Langmuir, 28(19), 7325 (2012)
Davoudinejad M, Ghorbanian SA, Sci. Res. Essay, 8, 2263 (2013)
Ghiaci M, Abbaspur A, Kia R, Seyedeyn-Azad F, Sep. Purif. Technol., 40(3), 217 (2004)
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Hinz c, Geoderma, 99, 225 (2001)
Limousin G, Gaudet JP, Charlet L, Szenknect S, Barthes V, Krimissa M, Appl. Geochem., 22, 249 (2007)
Sawhney BL, CMS Workshop Lectures, Sorption and Desorption of Organic Contaminants by Clays and Soils, The Clay Minerals Society Boulder, 1996.
Jaynes WF, Vance GF, Soil Sci. Soc. Am. J., 60, 1742 (1996)
Mortland MM, Shaobai S, Boyd SA, Clay Clay Min., 34(1), 581 (1986)
Akcay M, J. Colloid Interface Sci., 296(1), 16 (2006)
Lee S, Oren AH, Benson CH, Dovantzis K,, Geoenviron. Eng., 138, 115 (2012)
Smith JA, Jaffe PR, Chiou CT, Environ. Sci. Technol., 24, 1167 (1990)
Sheng GY, Xu SH, Boyd SA, Environ. Sci. Technol, 30, 1553 (1996)
Lee JF, Mortland MM, Chiou CT, Kile DE, Boyd SA, Clay Clay Min., 38, 113 (1990)
Zhu RH, Zhu LZ, Zhu JX, Xu LH, Sep. Purif. Technol., 63(1), 156 (2008)
Xing BS, McGill WB, Dudas MJ, Maham Y, Hepler L, Environ. Sci. Technol., 28, 466 (1994)
Boyd SA, Mortland MM, Chiou CT, Soil Sci. Soc. Am. J., 52, 652 (1988)
Lee JF, Crum JR, Boyd SA, Environ. Sci. Technol., 23, 1365 (1989)

[Referenced By]

[1] Qu F, Zhu LZ, Yang K, J. Hazard. Mater., 170(1), 7 (2009)

[2] Manjare SD, Ghoshal AK, Ind. Eng. Chem. Res., 45(19), 6563 (2006)

[3] Yu SJ, Wang XX, Ai YJ, Tan XL, Hayat T, Hu WP, Wang XK, J. Mater. Chem., 4, 5654 (2016)

[4] Jin ZX, Wang XX, Sun YB, Ai YJ, Wang XK, Environ. Sci. Technol., 49, 9168 (2015)

[5] Zaitan H, Bianchi D, Achak O, Chafik T, J. Hazard. Mater., 153(1-2), 852 (2008)

[6] Hu Q, Li JJ, Hao ZP, Li LD, Qiao SZ, Chem. Eng. J., 149(1-3), 281 (2009)

[7] Zou YD, Wang XX, Chen ZS, Yao W, Ai YJ, Liu TH, Hayat T, Alsaedi A, Alharbi NS, Wang XK, Environ. Pollut., 219, 107 (2016)

[8] Ko CH, Fan C, Chiang PN, Wang MK, Lin KC, J. Hazard. Mater., 149(2), 275 (2007)

[9] Richards S, Bouazza A, Appl. Clay Sci., 37, 133 (2007)

[10] Mangrulkar PA, Kamble SP, Meshram J, Rayalu SS, J. Hazard. Mater., 160(2-3), 414 (2008)

[11] Nunes CD, Pires J, Carvalho AP, Calhorda MJ, Ferreira P, Microporous Mesoporous Mater., 111, 612 (2008)

[12] Khenifi A, Zohra B, Kahina B, Houari H, Zoubir D, Chem. Eng. J., 146(3), 345 (2009)

[13] Gitipour S, Bowers MT, Huff W, Bodocsi A, Spill Sci. Technol. Bull., 4(3), 155 (1997)

[14] Gullick RW, Weber WJ, Environ. Sci. Technol., 35, 1523 (2001)

[15] Klapyta Z, Fujita T, Iyi N, Appl. Clay Sci., 19, 5 (2001)

[16] Klapyta Z, Gawel A, Fujita T, Iyi N, Clay Miner, 38, 151 (2003)

[17] Alba MA, Castro MA, Naranjo M, Pavon E, Chem. Mater., 18, 2867 (2006)

[18] Esfandiari A, Nazokdast H, Rashidi AS, Yazdanshenas ME, J. Appl. Sci., 8, 545 (2008)

[19] Alba MD, Castro MA, Orta MM, Pavon E, Pazos MC, Rios JSV, Langmuir, 27(16), 9711 (2011)

[20] Pazos MC, Castro MA, Orta MM, Pavon E, Rios JSV, Alba MD, Langmuir, 28(19), 7325 (2012)

[21] Davoudinejad M, Ghorbanian SA, Sci. Res. Essay, 8, 2263 (2013)

[22] Ghiaci M, Abbaspur A, Kia R, Seyedeyn-Azad F, Sep. Purif. Technol., 40(3), 217 (2004)

[23] Xu LH, Zhu LZ, Colloids Surf. A: Physicochem. Eng. Asp., 307, 1 (2007)

[24] Giles CH, Macewan TH, Nakhwa SN, Smith D, J. Chem. Soc. (1960) 3973.

[25] Hinz c, Geoderma, 99, 225 (2001)

[26] Limousin G, Gaudet JP, Charlet L, Szenknect S, Barthes V, Krimissa M, Appl. Geochem., 22, 249 (2007)

[27] Sawhney BL, CMS Workshop Lectures, Sorption and Desorption of Organic Contaminants by Clays and Soils, The Clay Minerals Society Boulder, 1996.

[28] Jaynes WF, Vance GF, Soil Sci. Soc. Am. J., 60, 1742 (1996)

[29] Mortland MM, Shaobai S, Boyd SA, Clay Clay Min., 34(1), 581 (1986)

[30] Akcay M, J. Colloid Interface Sci., 296(1), 16 (2006)

[31] Lee S, Oren AH, Benson CH, Dovantzis K,, Geoenviron. Eng., 138, 115 (2012)

[32] Smith JA, Jaffe PR, Chiou CT, Environ. Sci. Technol., 24, 1167 (1990)

[33] Sheng GY, Xu SH, Boyd SA, Environ. Sci. Technol, 30, 1553 (1996)

[34] Lee JF, Mortland MM, Chiou CT, Kile DE, Boyd SA, Clay Clay Min., 38, 113 (1990)

[35] Zhu RH, Zhu LZ, Zhu JX, Xu LH, Sep. Purif. Technol., 63(1), 156 (2008)

[36] Xing BS, McGill WB, Dudas MJ, Maham Y, Hepler L, Environ. Sci. Technol., 28, 466 (1994)

[37] Boyd SA, Mortland MM, Chiou CT, Soil Sci. Soc. Am. J., 52, 652 (1988)

[38] Lee JF, Crum JR, Boyd SA, Environ. Sci. Technol., 23, 1365 (1989)