화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.52, 260-269, August, 2017
DOI10.1016/j.jiec.2017.03.055  Export Citation
Conformal carbon layer coating on well-dispersed Si nanoparticles on graphene oxide and the enhanced electrochemical performance
Choa Kim1, Deepak Verma1, 2, Dong Ho Nam2, Wonyoung Chang3, and Jaehoon Kim1, 2, †
  • 1School of Mechanical Engineering, Sungkyunkwan University, 2066, Seobu-ro, Jangan-gu, Suwon, Gyeonggi-do 16419, Republic of Korea
  • 2SKKU Advanced Institute of Nano Technology (SAINT), Sungkyunkwan University, 2066, Seobu-ro, Jangan-gu, Suwon, Gyeonggi-do 16419, Republic of Korea
  • 3Center for Energy Convergence, Korea Institute of Science and Technology, Hwarangno 14-gil 5, Seongbuk-gu, Seoul 02792, Republic of Korea
E-mail:
Silicon nanoparticles (SiNPs).graphene oxide (GO) composites are synthesized using a simple, fast, and mild ball-milling route. Uniform and conformal carbon layer is coated on the surface of SiNPs and the carbon-coated SiNPs are well-dispersed on the GO matrix by forming Si-O-C linkages. A high reversible capacity of 1265 mA g-1 at 50 mA g-1 after 80 cycles, good rate capability of 238 mAh g-1 at 2.5 A g-1, and long-term cyclability of 230 mAh g-1 at 1 A g-1 after 800 cycles are resulted. The mild ballmilling can be highly promising and scalable approach for producing high-performance Si anode material.
Keywords:Ball milling;Silicon nanoparticles;Graphene oxide;Anode;Lithium-ion battery
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