As advanced electrodes for direct formic acid cells, nitrogen-doped graphene (NG) supported palladium-bismuth nanoparticles have been successfully fabricated through typical wet-chemical method. In studying the effects of NG support on PdBi nanoparticles for the electrooxidation of formic acid, we find that the as-prepared Pd1Bi1/NG network-like electrocatalysts exhibit much higher electrocatalytic activities than the Pd1Bi1/RGO, Pd1Bi1 and commercially available Pd/C catalysts in term of mass activity (1.69, 4.33 and 15.5times higher, respectively). The remarkably enhanced performances are associated with the electron transport between Bi and N, bi-functional effect between Pd, Bi and NG hybrids as well as the well-dispersed network-like structure on the surface of NG. The investigations of PdBi/NG in this work for promoting the electrocatalytic performances and the electron effect between Bi and N will accelerate the development for the field of direct formic acid fuel cells. (C) 2017 Elsevier B.V. All rights reserved.