Applied Surface Science, Vol.414, 68-72, 2017
Facile fabrication of plate-shaped hydrohausmannite as electrode material for supercapacitors
A simple and one-step solvothermal synthesis method has been developed to prepare two-dimensional (2-D) hydrohausmannite ((Mn4-2xMnx)Mn8O16-x(OH)(x)) nanoplates with radial length of 300 nm and thickness of about 25 nm in a binary ethanediamineiwater solvent system. The formation mechanism of hydrohausmannite is suggested. As an anode material for electrochemical capacitors, the plate-shaped hydrohausmannite not only displays a high specific capacity (215 at 0.1 A g(-1)) and good rate capability, but also shows good stable performance along with 94% specific capacity retained after 3000 cycle tests. The method can be easily controlled and expected to be applicable for the large-scale preparation of the 2-D hydrohausmannite. (C) 2017 Elsevier B.V. All rights reserved.