Applied Surface Science, Vol.411, 53-66, 2017
Improving interfacial, mechanical and tribological properties of alumina coatings on Al alloy by plasma arc heat-treatment of substrate
Plasma sprayed ceramic coatings can be used to improve the mechanical properties and wear resistance of aluminum alloys, but there are still some challenges to effectively increase their interfacial adhesion. Thus we conducted plasma arc-heat treatment (PA-HT) of Al alloy substrate before plasma spraying, hoping to tune the microstructure of Al2O3 coatings and improve their interfacial strength as well as mechanical and tribological properties. The influences of PA-HT on the microstructure of alumina coatings were analyzed by X-ray diffraction, transmission electron microscopy and scanning electron microscopy, while its effect on mechanical and tribological properties were evaluated by a nano-indentation tester and a friction and wear tester. Results demonstrate that a few columnar delta-Al2O3 generated on substrate surface after PA-HT at 200-250 degrees C can induce the epitaxial growth of gamma-Al2O3 grains in Al2O3 coatings, thereby enhancing their interfacial bonding. Besides, elevating substrate temperature can help alumina droplets to melt into the interior of substrate and eliminate holes at the interface, finally increasing the interfacial anchorage force. More importantly, no interfacial holes can allow the heat of droplets to be rapidly transmitted to substrate, which is beneficial to yield smaller crystals in coatings and greatly enhance their strength, hardness and wear resistance. (C) 2017 Elsevier B.V. All rights reserved.
Keywords:Al alloy;Ceramic coating;Epitaxial growth;Interfacial properties;Mechanical properties;Wear resistance