Journal of Physical Chemistry, Vol.100, No.25, 10768-10770, 1996
Fundamentals of the Diffuse Interface Theory of Nucleation
The basic assumptions of the diffuse interface theory of nucleation (bulk physical properties at the center of nuclei and size-independent interface thickness) are discussed in the light of field-theoretical calculations and light/X-ray reflectivity measurements. It is concluded that, contrary to recent suggestions, the basic assumptions of the diffuse interface theory are reasonable.
Keywords:LIQUID-VAPOR INTERFACE;HOMOGENEOUS NUCLEATION;COMPUTER-SIMULATION;TRIPLE POINT;N-NONANE;SURFACE;THERMODYNAMICS;CONDENSATION;THICKNESS