Structural supercapacitors can be considered as next-generation energy storage devices that have significant simultaneous performance characteristics in both structural applications and battery-like functions. In this study, we report the development of novel structural supercapacitors for the first time based on ZnO nanotubes, grown on woven carbon fiber electrodes, with a glass fiber separator. A solid polymer electrolyte is developed by mixing an ionic liquid (EMIMBF4), a lithium salt (LiTf), and polyaniline nano fiber with a polyester resin matrix. The supercapacitor is fabricated by a vacuum-assisted resin transfer molding process that is both effeCtive and eco-friendly. The specific capacitance of the supercapacitor enhances to 18.8 F g(-1), versus 0.2 F g(-1) for a bare carbon-fiber supercapacitor. Large increases in energy (156.2 mW h kg(-1)) and power density (19.87 W kg(-1)) are also achieved, with exceptional tensile strength (325 MPa) and modulus (21 GPa) values. The device demonstrates strong multifunctional performance so that it can be used confidently for energy storage in electric vehicles and unmanned aerial vehicles, and in the aerospace industry generally. (C) 2017 Elsevier B.V. All rights reserved.