화학공학소재연구정보센터
Industrial & Engineering Chemistry Research, Vol.56, No.15, 4600-4610, 2017
A Simple Correlation for Estimating the Viscosity of Pure Ionic Liquids and Their Binary Mixtures
Ionic liquids (ILs) have been of particular interest to researchers in recent years. Viscosity is considered as one of the most important thermophysical properties of ILs. This paper uses a genetic programming approach to propose a simple equation, with only one parameter to adjust, for predicting the viscosity of pure as and their binary mixtures as a function of temperature. The adjustable parameter of the equation was calculated for 103 pure ILs. The average absolute relative deviation of 4.60% obtained for 1374 data points confirms the good accuracy of the model. Also, an acceptable average absolute relative deviation of 12.83% at temperatures outside of the temperature range used to develop the model confirms the reliability of the model in the extrapolation of the temperature effect. To predict the viscosity of the binary mixture of ionic liquids by the proposed equation, the volumetric average of the parameter was applied to the proposed equation without introducing any new adjustable parameter. The average absolute relative deviation obtained for 954 data points comprised of 10 binary mixture of ionic liquids is 3.44%, which shows the good accuracy of the model in predicting the viscosity of a binary mixture of ionic liquids.