The preparation of nanocomposites of reduced graphene oxide with loaded TiO2 nanoparticles (TRGO) by a facile one-step hydrothermal treatment is reported. We have successfully increased the contact area of TiO2 and RGO to enhance polarization point, which is in favor of strengthening interfacial polarization. The interfaregioncial polarization has been regarded as an important role on the attenuation of high-frequency electromagnetic waves. Therefore, a good absorber is prepared by inserting the polarization point on the graphene aerogel, which shows excellent electromagnetic wave absorbing properties. In detail, the minimum reflection loss value at 2.1 mm is up to -27.2 dB for the TRGO-1.5 composite and the frequency bandwidth of 5.2 GHz can be obtained. Thus, it demonstrates that the adjustment of interface polarization would play a key role in the microwave-absorbing ability. (C) 2017 Elsevier Inc. All rights reserved.