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Journal of Power Sources, Vol.351, 1-7, 2017
Critical safety features of the vanadium redox flow battery
In this work the behaviour of the vanadium redox flow battery is examined under a variety of short-circuit conditions (e.g. with and without the pumps stopping as a result of the short). In contrast to other battery types, only a small proportion of the electroactive material, in a flow battery, is held between the electrodes at any given time. Therefore, together with the relatively low energy density of the vanadium electrolyte, the immediate release of energy, which occurs as a result of electrical shorting, is somewhat limited. The high heat capacity of the aqueous electrolyte is also beneficial in limiting the temperature rise. It will be seen that the flow battery is therefore considerably safer than other battery types, in this respect. (C) 2017 Elsevier B.V. All rights reserved.
Keywords:Vanadium redox flow battery;Short-circuit;Safety test;Thermal behaviour;Internal resistance