Stratification in binary colloidal mixtures was investigated using implicit-solvent molecular dynamics simulations. For large particle size ratios and film Peclet numbers greater than unity, smaller colloids migrated to the top of the film, while big colloids were pushed to the bottom, creating an "inverted" stratification. This peculiar behavior was observed in recent simulations and experiments conducted by Forthii et al. [Phys. Rev. Lett. 2016, 116, 118301]. To rationalize this behavior, particle size ratios and drying rates spanning qualitatively different Pedet number regimes were systematically studied, and the dynamics of the inverted stratification were quantified in detail. The stratified layer of small colloids was found to grow faster and to larger thicknesses for larger size ratios. Interestingly,, inverted stratification was observed even at moderate drying rates where the film Pedet numbers were comparable to unity, but the thickness of the stratified layer decreased. A model based on dynamical density functional theory is proposed to explain the observed phenomena.