화학공학소재연구정보센터
Materials Chemistry and Physics, Vol.194, 49-54, 2017
Zeolite-zeolite composite composed of Y zeolite and single-crystal-like ZSM-5 zeolite: Fabricated by a process like "big fish swallowing little one"
Zeolite-zeolite composite composed of Y and ZSM-5 zeolite was prepared using depolymerized Y as partial nutrients for the growth of ZSM-5. The as-synthesized samples were characterized by X-ray powder diffraction (XRD), FT-IR, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), transmission electron microscopy (TEM), N-2 adsorption-desorption measurement and Thermogravimetric analysis (TG). Chemical equilibrium at the solution-crystal interface was changed because of the partially depolymerized Y zeolite, the conditions necessary for the growth of ZSM-5 were therefore obtained. ZSM-5 zeolite crystals nucleated and grew on the interface, and Y zeolite crystals were then gradually swallowed by the growing single-crystal-like ZSM-5. (C) 2017 Elsevier B.V. All rights reserved.