Polymer, Vol.116, 439-446, 2017
Uniaxial and plane orientations of clay platelets in nanocomposite gels with different compositions during stretching and recovery
Changes in the birefringence (Delta n(NC)) of nanocomposite (NC) gels upon stretching and recovery were investigated for gels comprising a poly( N-isopropylacrylamide)-clay network structure. Irrespective of the composition of the NC gels, a change in the birefringence appeared upon stretching; DnNC varied greatly depending on the clay and water contents ( C-clay and C-w, respectively) of the gels and the stretching ratio. The NC gels with low Cclay gave rise to unique DnNC vs. strain curves with a maximum DnNC. For samples with higher Cclay, the variation of Delta n(NC)s observed in the edge-and through-directions, which is attributed to plane-orientation of the clay platelets, increased with increasing Cclay. This was confirmed by scanning electron microscopy observation, and the percentage plane-orientation was evaluated from the DnNC data. On recovery of the strain, the plane-oriented clay platelets underwent minimal reversion to the original state, although most of the PNIPA chains reverted to the random conformation. The effects of Cw on the Lambda n(NC)-strain curves were also clarified. (C) 2016 Elsevier Ltd. All rights reserved.