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Journal of Physical Chemistry A, Vol.101, No.16, 3042-3044, 1997
Heats of Formation of Alkyl Fluorides
Current data on Delta(f)H degrees(298) of alkyl fluorides are reexamined from the point of view of internal consistency and new values are recommended for all of them. In particular, fairly large discrepancies are suggested for current values of Delta(f)H degrees(298) of t-BuF, n-PrF, i-PrF, and EtF.
Keywords:BOND-DISSOCIATION ENERGIES;ELECTRONEGATIVITY SCALE;STABILIZATION ENERGIES;ALKYLSILANE DERIVATIVES;IONIZATION ENERGIES;MOLECULAR CATIONS;SUBSTITUTION;ALKANES;HALOALKANES;ENTHALPIES