화학공학소재연구정보센터
Thin Solid Films, Vol.635, 73-77, 2017
Indium tin oxide sputtering damage to catalytic chemical vapor deposited amorphous silicon passivation films and its recovery
We investigated the influence of indium tin oxide (ITO) sputtering damage to various types of amorphous silicon (a-Si) passivation films deposited by catalytic chemical vapor deposition. Intrinsic (i-) a-Si, n-type (n-) a-Si/i-a-Si, and p-type (p-) a-Si/i-a-Si stacked films were prepared on crystalline Si, and ITO was sputtered at various temperatures and RF powers, followed by post-annealing at 200 degrees C. Effective minority carrier lifetime (T-eff) of almost all the samples decreases drastically after sputtering, while T-eff of the samples with ITO sputtered at room temperature recovers significantly by post-annealing. Annealing before sputtering and sputtering at lower RF power leads to more effective recovery of T-eff The samples with ITO sputtered to an n-a-Si/i-a-Si stack show large T-eff recovery, while the samples with ITO sputtered to a p-a-Si/i-a-Si stack show much smaller T-eff recovery. T-eff recovery after ITO sputtering thus depends on the types of a-Si passivation films, which may be related to the modification of band alignment by the existence of ITO. (C) 2017 Elsevier B.V. All rights reserved.