Thin Solid Films, Vol.633, 40-44, 2017
Simulation of metastable changes in time resolved photoluminescence of Cu(In,Ga)Se-2 thin film solar cells upon light soaking treatment
Cu(In,Ga)Se-2 thin film solar cells are known to show a metastable behavior.of their open circuit voltage when exposed to light. Time resolved measurements of the photoluminescence decay after pulsed excitation (TRPL) reveal that also the photoluminescence decay (PL) changes with conditioning, yielding shorter effective lifetimes after annealing under illumination (light soaking) than after annealing in the dark. By using time resolved device simulations we applied a model that explains the TRPL metastable behavior. For this we used a model of capture and reemission of minority charge carriers via two characteristic trap states near the conduction band, while also accounting for changes in trap density and doping concentration caused by light soaking. To further understand the mechanisms behind PL decay we analyse the influence that the charge carrier dynamics play in TRPL decay by a variation of select simulation parameters. (C) 2016 Elsevier B.V. All rights reserved.