In this study the influence of low-temperature structural ordering in absorber material to the performance of Cu2ZnSnS4 (CZTS) monograin layer (MGL) solar cells was investigated. The shift of peak position in low temperature and room temperature photoluminescence measurements was used to estimate the Cu-Zn disorder level in CZTS monograin powders. The degree of Cu-Zn ordering was changed by using different cooling times after annealing CZTS powders in S atmosphere at 740 degrees C and by additional annealing at temperatures below critical temperature (T-c similar to 260 degrees C) for different time periods. Current-voltage measurements revealed that the low-temperature thermal treatments resulting in increased ordering of CZTS absorber material had significant impact on the MGL solar cell characteristics, mostly, the values of open circuit voltage (V-oc) were increased. The highest V-oc of 784 mV was measured for the solar cell based on the powder that was cooled from 740 degrees C to room temperature for 5 min followed by annealing at 150 degrees C for 24 h. Optimal conditions for low-temperature annealing to improve CZTS MGL solar cells' performance were found to be 4 hat 150 degrees C. These improvements resulted in CZTS MGL solar cell power conversion efficiency of 9.1% (active area). (C) 2016 Elsevier B.V. All rights reserved.