화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.53, 294-306, September, 2017
DOI10.1016/j.jiec.2017.04.038  Export Citation
Facile synthesis of Lead Doped Zinc-Aluminum Oxide Nanoparticles (LD-ZAO-NPs) for efficient adsorption of anionic dye: Kinetic, isotherm and thermodynamic behaviors
Ganesh Jethave, Umesh Fegade1, Sanjay Attarde†, and Sopan Ingle
  • School of Environmental and Earth Sciences, North Maharashtra University, Jalgaon,MS, India
  • 1Bhusawal Arts, Science and P. O. Nahata Commerce College, Bhusawal, MS, India
E-mail:
New LD-ZAO-NPs was facilely synthesized and characterized by FESEM, XRD, EDX and FT IR. Under the optimal conditions, the MO removal efficiency reached 99.60% after 30 min, Langmuir isotherm and a pseudo second-order kinetic model showed high performance. The thermodynamic parameters showed that the adsorption was spontaneous and favorable as ΔG0 is negative and exothermic in nature as ΔH0 is negative (-0.025 kJ/mol). The maximum adsorption capacity (qmax) in single component system 200 mg g-1 for MO supports high efficiency of LD-ZAO-NPs as new adsorbent. Altogether, the superior performance of LD-ZAO-NPs was manifested by fast kinetics and high adsorption capacity.
Keywords:Facile synthesis;LD-ZAONPs;Methyl Orange;Kinetics;Thermodypnamics
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