Construction and adhesion performance of biomass tetrahydro-geraniol-based sustainable/transparent pressure sensitive adhesives

Seung-Suk Baek; Su-Hee Jang; Seok-Ho Hwang

Journal of Industrial and Engineering Chemistry, Vol.53, 429-434, September, 2017

DOI10.1016/j.jiec.2017.05.017 Export Citation

Construction and adhesion performance of biomass tetrahydro-geraniol-based sustainable/transparent pressure sensitive adhesives

Seung-Suk Baek, Su-Hee Jang, and Seok-Ho Hwang^†

Department of Polymer Science & Engineering, Materials Chemistry & Engineering Laboratory, Dankook University, Yongin, Gyeonggi 16890, Republic of Korea

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Using the tetrahydro-geraniol acrylate (TGA) synthesized from biomass tetrahydro-geraniol, U -cured transparent acrylic pressure sensitive adhesives (PSAs) composed of semi interpenetrating networks were successfully fabricated. The utility for optically clear adhesive on adhesion performances according to various concentrations of TGA in the acrylic PSAs were investigated. After characterizing the photo- polymerized PSA syrups, the optical properties for the acrylic PSA films were examined using UV.vis spectroscopy, a color-difference meter, and a haze meter. The acrylic PSAs exhibited high transparency and stable weather-ability under reliability testing (85/85 test). With increasing TGA concentration in the acrylic PSAs, adhesionpropertiessuch asthe180 peel strength,shearholdingpower,andprobe tack haddecreased.

Keywords:Pressure sensitive adhesive;Tetrahydro-geraniol;Biomass;Adhesion;Transparency

[References]

Pu G, Dubay MR, Zhang JG, Severtson SJ, Ind. Eng. Chem. Res., 51(37), 12145 (2012)
Brown RC, Brown TR, Biorenewable Resources: Engineering New Products from Agriculture, 2nd ed., John Wiley & Sons, West Sussex, 2014.
Stevens ES, Green Plastics: An Introduction to the New Science of Biodegradable Plastics, Princeton University Press, Princeton, 2002.
Arbaoui A, Redshaw C, Polym. Chem., 1, 801 (2010)
Minami M, Kozaki S, US Patent 6 559 275, 2003.
Martello MT, Hillmyer MA, Macromolecules, 44(21), 8537 (2011)
Bunker S, Staller C, Willenbacher N, Wool RP, Int. J. Adhes. Adhes., 23, 29 (2003)
Bunker SP, Wool RP, J. Polym. Sci. A: Polym. Chem., 40(4), 451 (2002)
Klapperich CM, Noack CL, Kaufman JD, Zhu L, Bonnaillie L, Wool RP, J. Biomed. Mater. Res., 91A, 378 (2009)
Baek SS, Hwang SH, Polym. Bull., 73(3), 687 (2016)
Beak SS, Hong S, Hwang SH, Polym. Korea, 40(5), 678 (2016)
Baek SS, Hwang SH, Int. J. Adhes. Adhes., 70, 110 (2016)
Miyamoto M, Ohta A, Kawata Y, Nakabayashi M, Jpn. J. Appl. Phys., 46, 3978 (2007)
Yue H, Zhao Y, Ma X, Gong J, Chem. Soc. Rev., 41, 4218 (2012)
Battersby AR, Laing DG, Ramage R, J. Chem. Soc.-Perkin Trans. 1, 2743 (1972)
Croteau R, Satterwhite DM, Cane DE, Chang CC, J. Biol. Chem., 261, 1986 (1343)
Pigłowski J, Kozłowski M, Rheol. Acta, 24, 519 (1985)
Lim DH, Do HS, Kim HJ, J. Appl. Polym. Sci., 102(3), 2839 (2006)
Taghizadeh SM, Ghasemi D, J. Appl. Polym. Sci., 120(1), 411 (2011)
Ho YK, Dodou K, Int. J. Pharm., 333, 24 (2007)
Satas D, Handbook of Pressure Sensitive Adhesives, Van Nostrand-Reinhold, New York, 1989, pp. 396.
Taghizadeh SM, Mirzadeh H, Barikani M, Yousefi M, Iran. Polym. J., 16, 279 (2007)
Kenney JF, Haddock TH, Sun RL, Parreira HC, J. Appl. Polym. Sci., 45, 355 (1992)
Chan LW, Wong TW, Chua PC, York P, Heng PWS, Chem. Pharm. Bull., 51, 107 (2003)
Hock CW, Abbott AN, Rubber Age, 82, 471 (1957)
Taghizadeh SM, Mirzadeh H, Barikani M, Yousefi M, Int. J. Adhes. Adhes., 29, 302 (2009)
Tobing SD, Klein A, J. Appl. Polym. Sci., 79(12), 2230 (2001)
Wetzel FH, Rubber Age, 82, 291 (1957)

[Referenced By]

[1] Pu G, Dubay MR, Zhang JG, Severtson SJ, Ind. Eng. Chem. Res., 51(37), 12145 (2012)

[2] Brown RC, Brown TR, Biorenewable Resources: Engineering New Products from Agriculture, 2nd ed., John Wiley & Sons, West Sussex, 2014.

[3] Stevens ES, Green Plastics: An Introduction to the New Science of Biodegradable Plastics, Princeton University Press, Princeton, 2002.

[4] Arbaoui A, Redshaw C, Polym. Chem., 1, 801 (2010)

[5] Minami M, Kozaki S, US Patent 6 559 275, 2003.

[6] Martello MT, Hillmyer MA, Macromolecules, 44(21), 8537 (2011)

[7] Bunker S, Staller C, Willenbacher N, Wool RP, Int. J. Adhes. Adhes., 23, 29 (2003)

[8] Bunker SP, Wool RP, J. Polym. Sci. A: Polym. Chem., 40(4), 451 (2002)

[9] Klapperich CM, Noack CL, Kaufman JD, Zhu L, Bonnaillie L, Wool RP, J. Biomed. Mater. Res., 91A, 378 (2009)

[10] Baek SS, Hwang SH, Polym. Bull., 73(3), 687 (2016)

[11] Beak SS, Hong S, Hwang SH, Polym. Korea, 40(5), 678 (2016)

[12] Baek SS, Hwang SH, Int. J. Adhes. Adhes., 70, 110 (2016)

[13] Miyamoto M, Ohta A, Kawata Y, Nakabayashi M, Jpn. J. Appl. Phys., 46, 3978 (2007)

[14] Yue H, Zhao Y, Ma X, Gong J, Chem. Soc. Rev., 41, 4218 (2012)

[15] Battersby AR, Laing DG, Ramage R, J. Chem. Soc.-Perkin Trans. 1, 2743 (1972)

[16] Croteau R, Satterwhite DM, Cane DE, Chang CC, J. Biol. Chem., 261, 1986 (1343)

[17] Pigłowski J, Kozłowski M, Rheol. Acta, 24, 519 (1985)

[18] Lim DH, Do HS, Kim HJ, J. Appl. Polym. Sci., 102(3), 2839 (2006)

[19] Taghizadeh SM, Ghasemi D, J. Appl. Polym. Sci., 120(1), 411 (2011)

[20] Ho YK, Dodou K, Int. J. Pharm., 333, 24 (2007)

[21] Satas D, Handbook of Pressure Sensitive Adhesives, Van Nostrand-Reinhold, New York, 1989, pp. 396.

[22] Taghizadeh SM, Mirzadeh H, Barikani M, Yousefi M, Iran. Polym. J., 16, 279 (2007)

[23] Kenney JF, Haddock TH, Sun RL, Parreira HC, J. Appl. Polym. Sci., 45, 355 (1992)

[24] Chan LW, Wong TW, Chua PC, York P, Heng PWS, Chem. Pharm. Bull., 51, 107 (2003)

[25] Hock CW, Abbott AN, Rubber Age, 82, 471 (1957)

[26] Taghizadeh SM, Mirzadeh H, Barikani M, Yousefi M, Int. J. Adhes. Adhes., 29, 302 (2009)

[27] Tobing SD, Klein A, J. Appl. Polym. Sci., 79(12), 2230 (2001)

[28] Wetzel FH, Rubber Age, 82, 291 (1957)